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dc.creatorMorales, Maria Roxana-
dc.creatorYeste, M. Pilar-
dc.creatorVidal, Hilario-
dc.creatorGatica, José M.-
dc.creatorCadus, Luis Eduardo-
dc.date2018-11-14T14:27:14Z-
dc.date2018-11-14T14:27:14Z-
dc.date2017-11-
dc.date2018-10-23T17:40:01Z-
dc.date.accessioned2019-04-29T15:27:51Z-
dc.date.available2019-04-29T15:27:51Z-
dc.date.issued2018-11-14T14:27:14Z-
dc.date.issued2018-11-14T14:27:14Z-
dc.date.issued2017-11-
dc.date.issued2018-10-23T17:40:01Z-
dc.identifierMorales, Maria Roxana; Yeste, M. Pilar; Vidal, Hilario; Gatica, José M.; Cadus, Luis Eduardo; Insights on the combustion mechanism of ethanol and n-hexane in honeycomb monolithic type catalysts: Influence of the amount and nature of Mn-Cu mixed oxide; Elsevier; Fuel; 208; 11-2017; 637-646-
dc.identifier0016-2361-
dc.identifierhttp://hdl.handle.net/11336/64450-
dc.identifierCONICET Digital-
dc.identifierCONICET-
dc.identifier.urihttp://rodna.bn.gov.ar:8080/jspui/handle/bnmm/294619-
dc.descriptionMn-Cu mixed oxides were deposited by ultrasonic impregnation on ceramic honeycomb monoliths. Its catalytic performance was evaluated in the combustion of ethanol and n-hexane, VOC molecules of different chemical nature. The catalysts were characterized by N2 physisorption, SEM-EDS, XRD, X-ray fluorescence, XPS, TPR, TPD-O2 and OSC measurements. It was observed that the catalyst with the lowest content of Mn-Cu phase was the most active in the combustion of ethanol. This was attributed to the higher content of Mn4+ and the increase of lattice oxygen mobility, which would favor a Mars-van Krevelen type mechanism. The catalyst with a medium content of Mn-Cu, proved to be the most active in the combustion of n-hexane. This was associated with a high content of oxygen vacancies and easy availability of oxygen adsorbed on the surface, promoting the combustion of n-hexane, possibly through a Rideal-Eley type mechanism. The catalyst with the highest content of the Mn-Cu phase showed low activity in combustion of ethanol and n-hexane, which was attributed to a higher crystallinity of the Mn-Cu phases generated.-
dc.descriptionFil: Morales, Maria Roxana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina-
dc.descriptionFil: Yeste, M. Pilar. Universidad de Cádiz; España-
dc.descriptionFil: Vidal, Hilario. Universidad de Cádiz; España-
dc.descriptionFil: Gatica, José M.. Universidad de Cádiz; España-
dc.descriptionFil: Cadus, Luis Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina-
dc.formatapplication/pdf-
dc.formatapplication/pdf-
dc.languageeng-
dc.publisherElsevier-
dc.relationinfo:eu-repo/semantics/altIdentifier/url/http://linkinghub.elsevier.com/retrieve/pii/S0016236117309316-
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/https://dx.doi.org/10.1016/j.fuel.2017.07.069-
dc.rightsinfo:eu-repo/semantics/restrictedAccess-
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/-
dc.sourcereponame:CONICET Digital (CONICET)-
dc.sourceinstname:Consejo Nacional de Investigaciones Científicas y Técnicas-
dc.sourceinstacron:CONICET-
dc.subjectCORDIERITE-
dc.subjectETHANOL-
dc.subjectMANGANESE-COPPER MIXED OXIDE-
dc.subjectN-HEXANE-
dc.subjectVOC OXIDATION-
dc.subjectOtras Ingeniería Química-
dc.subjectIngeniería Química-
dc.subjectINGENIERÍAS Y TECNOLOGÍAS-
dc.titleInsights on the combustion mechanism of ethanol and n-hexane in honeycomb monolithic type catalysts: Influence of the amount and nature of Mn-Cu mixed oxide-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/publishedVersion-
dc.typeinfo:ar-repo/semantics/articulo-
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