Registro completo de metadatos
| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.creator | Quaino, Paola Monica | - |
| dc.creator | Schmickler, Wolfgang | - |
| dc.date | 2017-12-21T19:47:20Z | - |
| dc.date | 2017-12-21T19:47:20Z | - |
| dc.date | 2014-03 | - |
| dc.date | 2017-12-21T14:06:26Z | - |
| dc.date.accessioned | 2019-04-29T15:29:10Z | - |
| dc.date.available | 2019-04-29T15:29:10Z | - |
| dc.date.issued | 2017-12-21T19:47:20Z | - |
| dc.date.issued | 2017-12-21T19:47:20Z | - |
| dc.date.issued | 2014-03 | - |
| dc.date.issued | 2017-12-21T14:06:26Z | - |
| dc.identifier | Schmickler, Wolfgang; Quaino, Paola Monica; Oxygen-Terminated Diamond Electrodes in Alkaline Media: Structure and OH Generation; Wiley; ChemElectroChem; 1; 5; 3-2014; 933-939 | - |
| dc.identifier | 2196-0216 | - |
| dc.identifier | http://hdl.handle.net/11336/31270 | - |
| dc.identifier | CONICET Digital | - |
| dc.identifier | CONICET | - |
| dc.identifier.uri | http://rodna.bn.gov.ar:8080/jspui/handle/bnmm/295002 | - |
| dc.description | The structure and energetics of two types of oxygen-terminated diamond surfaces, the keto and ether configurations, were investigated by density functional theory. To explore OH generation, we studied the approach of a hydroxyl radical to these surfaces. The OH radical strongly interacted with the ether-type surface, whereas the radical was repelled in the keto configuration. The kinetics of OH generation in alkaline solutions (OH−↔OH+e−) on oxygen-terminated diamond electrodes was investigated in light of the theory of catalyzed electron transfer. Our results suggested that the electron transfer occurs in the outer-sphere mode with an activation energy of 0.5 eV. | - |
| dc.description | Fil: Quaino, Paola Monica. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina | - |
| dc.description | Fil: Schmickler, Wolfgang. Universitat Ulm; Alemania. Institute of Theoretical Chemistry; Alemania | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.language | eng | - |
| dc.publisher | Wiley | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/celc.201300200/abstract | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1002/celc.201300200 | - |
| dc.rights | info:eu-repo/semantics/restrictedAccess | - |
| dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | - |
| dc.source | reponame:CONICET Digital (CONICET) | - |
| dc.source | instname:Consejo Nacional de Investigaciones Científicas y Técnicas | - |
| dc.source | instacron:CONICET | - |
| dc.subject | OXYGEN-TERMINATED DIAMOND | - |
| dc.subject | ALKALINE MEDIA | - |
| dc.subject | OH GENERATION | - |
| dc.subject | Otras Ciencias Químicas | - |
| dc.subject | Ciencias Químicas | - |
| dc.subject | CIENCIAS NATURALES Y EXACTAS | - |
| dc.title | Oxygen-Terminated Diamond Electrodes in Alkaline Media: Structure and OH Generation | - |
| dc.type | info:eu-repo/semantics/article | - |
| dc.type | info:eu-repo/semantics/publishedVersion | - |
| dc.type | info:ar-repo/semantics/articulo | - |
| Aparece en las colecciones: | CONICET | |
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