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Campo DC | Valor | Lengua/Idioma |
---|---|---|
dc.creator | Guastavino, Javier Fernando | - |
dc.creator | Rossi, Roberto Arturo | - |
dc.date | 2017-01-09T13:20:04Z | - |
dc.date | 2017-01-09T13:20:04Z | - |
dc.date | 2012-01 | - |
dc.date | 2017-01-05T15:01:44Z | - |
dc.date.accessioned | 2019-04-29T15:29:19Z | - |
dc.date.available | 2019-04-29T15:29:19Z | - |
dc.date.issued | 2017-01-09T13:20:04Z | - |
dc.date.issued | 2017-01-09T13:20:04Z | - |
dc.date.issued | 2012-01 | - |
dc.date.issued | 2017-01-05T15:01:44Z | - |
dc.identifier | Guastavino, Javier Fernando; Rossi, Roberto Arturo; Synthesis of Benzo-Fused Heterocycles by Intramolecular alpha-Arylation of Ketone Enolate Anions; American Chemical Society; Journal Of Organic Chemistry; 77; 1; 1-2012; 460-472 | - |
dc.identifier | 0022-3263 | - |
dc.identifier | http://hdl.handle.net/11336/10963 | - |
dc.identifier.uri | http://rodna.bn.gov.ar:8080/jspui/handle/bnmm/295064 | - |
dc.description | A two-step synthesis of six-, seven-, eight-, and nine-member benzo-fused heterocycles in good to excellent yields is reported. The synthetic strategy involves the generation of a new intramolecular alpha-aryl ketone bond by the photostimulated SRN1 reaction of ketone enolate anions linked to a pendant haloarene as the key step. On the other hand, an intramolecular CAr-CAr coupling led to the formation of five- and six-member benzo-fused heterocycles (9H-carbazole and phenanthridine) when an aromatic amide anion is competitively formed | - |
dc.description | Fil: Guastavino, Javier Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Investigaciones en Físicoquímica de Córdoba; Argentina. Universidad Nacional de Córdoba; Argentina | - |
dc.description | Fil: Rossi, Roberto Arturo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Investigaciones en Físicoquímica de Córdoba; Argentina. Universidad Nacional de Córdoba; Argentina | - |
dc.format | application/pdf | - |
dc.format | application/pdf | - |
dc.language | eng | - |
dc.publisher | American Chemical Society | - |
dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1021/jo202012n | - |
dc.relation | info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/jo202012n | - |
dc.rights | info:eu-repo/semantics/restrictedAccess | - |
dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | - |
dc.source | reponame:CONICET Digital (CONICET) | - |
dc.source | instname:Consejo Nacional de Investigaciones Científicas y Técnicas | - |
dc.source | instacron:CONICET | - |
dc.subject | BENZO-FUSED HETEROCYCLES | - |
dc.subject | SRN1 REACTIONS | - |
dc.subject | KETONE ENOLATE ANIONS | - |
dc.subject | ARYLATION | - |
dc.subject | ALPHA-ARYL KETONE | - |
dc.subject | Química Orgánica | - |
dc.subject | Ciencias Químicas | - |
dc.subject | CIENCIAS NATURALES Y EXACTAS | - |
dc.title | Synthesis of Benzo-Fused Heterocycles by Intramolecular alpha-Arylation of Ketone Enolate Anions | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/publishedVersion | - |
dc.type | info:ar-repo/semantics/articulo | - |
Aparece en las colecciones: | CONICET |
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