Registro completo de metadatos
| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.creator | Lopez, Carlos Alberto | - |
| dc.creator | Saleta, Martin Eduardo | - |
| dc.creator | Pedregosa, Jose Carmelo | - |
| dc.creator | Sanchez, Rodolfo Daniel | - |
| dc.creator | Lamas, D. G. | - |
| dc.creator | Alonso, J. A. | - |
| dc.creator | Fernández Díaz, M. T. | - |
| dc.date | 2016-05-24T19:04:13Z | - |
| dc.date | 2016-05-24T19:04:13Z | - |
| dc.date | 2015-12 | - |
| dc.date | 2016-05-16T20:09:20Z | - |
| dc.date.accessioned | 2019-04-29T15:31:02Z | - |
| dc.date.available | 2019-04-29T15:31:02Z | - |
| dc.date.issued | 2015-12 | - |
| dc.identifier | Lopez, Carlos Alberto; Saleta, Martin Eduardo; Pedregosa, Jose Carmelo; Sanchez, Rodolfo Daniel; Lamas, D. G.; et al.; Electronic properties in intrinsically disordered double perovskites: Sr3MnMo2O9 and Ba3MnMo2O9 with Mo5+ valence state; Elsevier; Journal of Alloys and Compounds; 661; 12-2015; 411-418 | - |
| dc.identifier | 0925-8388 | - |
| dc.identifier | http://hdl.handle.net/11336/5819 | - |
| dc.identifier.uri | http://rodna.bn.gov.ar:8080/jspui/handle/bnmm/295567 | - |
| dc.description | Sr3MnMo2O9 and Ba3MnMo2O9 double perovskites with Mo5+ valence states have been prepared in polycrystalline form by thermal treatment, in reducing atmosphere (H2/N2 flow), of previously decomposed citrate precursors. These materials have been studied by X-ray and neutron powder diffraction (XRPD, NPD), magnetic and transport measurements. At room temperature, the crystal structure of Sr3MnMo2O9 is monoclinic, space group P21/n, with a = 5.6564(1) Å, b = 5.6383(1) Å, c = 7.9765(2) Å, beta = 89.994(7)°; whereas Ba3MnMo2O9 presents a cubic lattice, space group Fm-3m, with a = 8.14900(8) Å. These samples present a frustrated magnetic interaction below to 12 and 9 K for Sr3MnMo2O9 and Ba3MnMo2O9, respectively. Semiconductor behaviour, observed either from d.c. or a.c. measurements, was modelled by a variable-range hopping mechanism. This transport behaviour is in accord with the electronic configurations Mn2+(3d5)-Mo5+(4d1) and supports the absence of mixed valence states in both double perovkites. | - |
| dc.description | Fil: Lopez, Carlos Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Investigaciones En Tecnología Química; Argentina | - |
| dc.description | Fil: Saleta, Martin Eduardo. Comisión Nacional de Energía Atómica. Gerencia del Area de Investigación y Aplicaciones No Nucleares. Gerencia de Física. Laboratorio de Resonancias Magnéticas; Argentina | - |
| dc.description | Fil: Pedregosa, Jose Carmelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Investigaciones En Tecnología Química; Argentina | - |
| dc.description | Fil: Sanchez, Rodolfo Daniel. Comisión Nacional de Energía Atómica. Gerencia del Area de Investigación y Aplicaciones No Nucleares. Gerencia de Física. Laboratorio de Resonancias Magnéticas; Argentina | - |
| dc.description | Fil: Lamas, D. G.. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina | - |
| dc.description | Fil: Alonso, J. A.. Instituto de Ciencia de Materiales de Madrid; España | - |
| dc.description | Fil: Fernández Díaz, M. T.. Institut Laue Langevin; Francia | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.language | eng | - |
| dc.publisher | Elsevier | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0925838815317618 | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.jallcom.2015.11.204 | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jallcom.2015.11.204 | - |
| dc.rights | info:eu-repo/semantics/restrictedAccess | - |
| dc.rights | https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ | - |
| dc.source | reponame:CONICET Digital (CONICET) | - |
| dc.source | instname:Consejo Nacional de Investigaciones Científicas y Técnicas | - |
| dc.source | instacron:CONICET | - |
| dc.subject | INORGANIC MATERIALS | - |
| dc.subject | CRYSTAL STRUCTURE | - |
| dc.subject | ELECTRONIC PROPERTIES | - |
| dc.subject | MAGNETIC MEASUREMENTS | - |
| dc.subject | NEUTRON DIFFRACTIONS | - |
| dc.subject | IMPEDANCE SPECTROSCOPY | - |
| dc.subject | Química Inorgánica y Nuclear | - |
| dc.subject | Ciencias Químicas | - |
| dc.subject | CIENCIAS NATURALES Y EXACTAS | - |
| dc.title | Electronic properties in intrinsically disordered double perovskites: Sr3MnMo2O9 and Ba3MnMo2O9 with Mo5+ valence state | - |
| dc.type | info:eu-repo/semantics/article | - |
| dc.type | info:eu-repo/semantics/publishedVersion | - |
| dc.type | info:ar-repo/semantics/articulo | - |
| Aparece en las colecciones: | CONICET | |
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