Registro completo de metadatos
| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.creator | Gil, Diego Mauricio | - |
| dc.creator | Osiry, Hernández | - |
| dc.creator | Pomiro, Fernando | - |
| dc.creator | Varetti, Eduardo Lelio | - |
| dc.creator | Carbonio, Raul Ernesto | - |
| dc.creator | Alejandro, R. R. | - |
| dc.creator | Ben Altabef, Aída | - |
| dc.creator | Reguera, Edilso | - |
| dc.date | 2017-10-25T18:03:27Z | - |
| dc.date | 2017-10-25T18:03:27Z | - |
| dc.date | 2016-04 | - |
| dc.date | 2017-10-17T13:40:01Z | - |
| dc.date.accessioned | 2019-04-29T15:31:50Z | - |
| dc.date.available | 2019-04-29T15:31:50Z | - |
| dc.date.issued | 2016-04 | - |
| dc.identifier | Gil, Diego Mauricio; Osiry, Hernández; Pomiro, Fernando; Varetti, Eduardo Lelio; Carbonio, Raul Ernesto; et al.; Layered vanadyl (IV) nitroprusside: Magnetic interaction through a network of hydrogen bonds; Elsevier Inc; Journal of Solid State Chemistry; 239; 4-2016; 159-164 | - |
| dc.identifier | 0022-4596 | - |
| dc.identifier | http://hdl.handle.net/11336/27090 | - |
| dc.identifier | CONICET Digital | - |
| dc.identifier | CONICET | - |
| dc.identifier.uri | http://rodna.bn.gov.ar:8080/jspui/handle/bnmm/295871 | - |
| dc.description | The hydrogen bond and π-π stacking are two non-covalent interactions able to support cooperative magnetic ordering between paramagnetic centers. This contribution reports the crystal structure and related magnetic properties for VO[Fe(CN)5NO]·2H2O, which has a layered structure. This solid crystallizes with an orthorhombic unit cell, in the Pna21 space group, with cell parameters a=14.1804(2), b=10.4935(1), c=7.1722(8) Å and four molecules per unit cell (Z=4). Its crystal structure was solved and refined from powder X-ray diffraction data. Neighboring layers remain linked through a network of hydrogen bonds involving a water molecule coordinated to the axial position for the V atom and the unbridged axial NO and CN ligands. An uncoordinated water molecule is found forming a triple bridge between these last two ligands and the coordinated water molecule. The magnetic measurements, recorded down to 2 K, shows a ferromagnetic interaction between V atoms located at neighboring layers, with a Curie-Weiss constant of 3.14 K. Such ferromagnetic behavior was interpreted as resulting from a superexchange interaction through the network of strong OH····OH2O, OH····NCN, and OH····ONO hydrogen bonds that connects neighboring layers. The interaction within the layer must be of antiferromagnetic nature and it was detected close to 2 K. | - |
| dc.description | Fil: Gil, Diego Mauricio. Universidad Nacional de Tucuman. Facultad de Bioquímica, Química y Farmacia. Instituto de Química Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina | - |
| dc.description | Fil: Osiry, Hernández. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; México | - |
| dc.description | Fil: Pomiro, Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; Argentina | - |
| dc.description | Fil: Varetti, Eduardo Lelio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; Argentina | - |
| dc.description | Fil: Carbonio, Raul Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina | - |
| dc.description | Fil: Alejandro, R. R.. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; México | - |
| dc.description | Fil: Ben Altabef, Aída. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; Argentina | - |
| dc.description | Fil: Reguera, Edilso. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; México | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.language | eng | - |
| dc.publisher | Elsevier Inc | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.jssc.2016.04.025 | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0022459616301578 | - |
| dc.rights | info:eu-repo/semantics/restrictedAccess | - |
| dc.rights | https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ | - |
| dc.source | reponame:CONICET Digital (CONICET) | - |
| dc.source | instname:Consejo Nacional de Investigaciones Científicas y Técnicas | - |
| dc.source | instacron:CONICET | - |
| dc.subject | NITROPRUSSIDE | - |
| dc.subject | MOLECULAR MAGNETISM | - |
| dc.subject | HYDROGEN BONDS | - |
| dc.subject | LAYERED SOLID | - |
| dc.subject | VANADYL | - |
| dc.subject | Otras Ciencias Químicas | - |
| dc.subject | Ciencias Químicas | - |
| dc.subject | CIENCIAS NATURALES Y EXACTAS | - |
| dc.title | Layered vanadyl (IV) nitroprusside: Magnetic interaction through a network of hydrogen bonds | - |
| dc.type | info:eu-repo/semantics/article | - |
| dc.type | info:eu-repo/semantics/publishedVersion | - |
| dc.type | info:ar-repo/semantics/articulo | - |
| Aparece en las colecciones: | CONICET | |
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