Registro completo de metadatos
| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.creator | Montemurro, Milagros | - |
| dc.creator | Siano, Gabriel German | - |
| dc.creator | Alcaraz, Mirta Raquel | - |
| dc.creator | Goicoechea, Hector Casimiro | - |
| dc.date | 2018-01-17T18:09:04Z | - |
| dc.date | 2018-01-17T18:09:04Z | - |
| dc.date | 2017-08 | - |
| dc.date | 2018-01-02T14:02:50Z | - |
| dc.date.accessioned | 2019-04-29T15:32:34Z | - |
| dc.date.available | 2019-04-29T15:32:34Z | - |
| dc.date.issued | 2018-01-17T18:09:04Z | - |
| dc.date.issued | 2018-01-17T18:09:04Z | - |
| dc.date.issued | 2017-08 | - |
| dc.date.issued | 2018-01-02T14:02:50Z | - |
| dc.identifier | Siano, Gabriel German; Montemurro, Milagros; Goicoechea, Hector Casimiro; Alcaraz, Mirta Raquel; Third order chromatographic-excitation–emission fluorescence data: Advances, challenges and prospects in analytical applications; Elsevier; Trac-Trends In Analytical Chemistry; 93; 8-2017; 119-133 | - |
| dc.identifier | 0165-9936 | - |
| dc.identifier | http://hdl.handle.net/11336/33646 | - |
| dc.identifier | CONICET Digital | - |
| dc.identifier | CONICET | - |
| dc.identifier.uri | http://rodna.bn.gov.ar:8080/jspui/handle/bnmm/296130 | - |
| dc.description | Three analytical methodologies for the generation of third-order liquid chromatography–excitation–emission fluorescence matrix (LC–EEM) data are presented. Instrumental requirements were evaluated considering equipment complexity, costs and accessibility. A descriptive analysis of the generated data was done along trilinearity concept and chemometric resolution. For trilinear decomposition, PARallel FACtor Analysis (PARAFAC) model was utilized. Hence, possible effects that are caused in the resolution due to loss of trilinearity are detailed. Then, several data pre-processing and processing alternatives are proposed in order to successfully overcome the drawbacks that can be present in the chemometric resolution. Additionally, a reported analytical method for the determination of three analytes is presented to showcase the potential of the methodology to generate third-order LC–EEM data with quantitative aims. For data modelling, Augmented PARAFAC (APARAFAC) and Multivariate Curve Resolution-Alternating Least Squares (MCR-ALS) were used. Both algorithms demonstrated to be able to bear non-quadrilinear data in a multi-set analysis. | - |
| dc.description | Fil: Montemurro, Milagros. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina | - |
| dc.description | Fil: Siano, Gabriel German. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; Argentina | - |
| dc.description | Fil: Alcaraz, Mirta Raquel. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina | - |
| dc.description | Fil: Goicoechea, Hector Casimiro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; Argentina | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.language | eng | - |
| dc.publisher | Elsevier | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.trac.2017.05.011 | - |
| dc.rights | info:eu-repo/semantics/restrictedAccess | - |
| dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | - |
| dc.source | reponame:CONICET Digital (CONICET) | - |
| dc.source | instname:Consejo Nacional de Investigaciones Científicas y Técnicas | - |
| dc.source | instacron:CONICET | - |
| dc.subject | EXCITATION–EMISSION FLUORESCENCE MATRIX | - |
| dc.subject | LIQUID CHROMATOGRAPHY | - |
| dc.subject | MULTI-WAY ANALYSIS | - |
| dc.subject | THIRD-ORDER DATA | - |
| dc.subject | TRILINEAR DECOMPOSITION | - |
| dc.subject | Otras Ciencias Químicas | - |
| dc.subject | Ciencias Químicas | - |
| dc.subject | CIENCIAS NATURALES Y EXACTAS | - |
| dc.title | Third order chromatographic-excitation–emission fluorescence data: Advances, challenges and prospects in analytical applications | - |
| dc.type | info:eu-repo/semantics/article | - |
| dc.type | info:eu-repo/semantics/publishedVersion | - |
| dc.type | info:ar-repo/semantics/articulo | - |
| Aparece en las colecciones: | CONICET | |
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