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dc.provenanceCONICET-
dc.creatorBonin, Claudio Julio-
dc.creatorGonzález, C. E.-
dc.creatorSegnorile, Hector Hugo-
dc.creatorZamar, Ricardo César-
dc.date2016-02-25T17:40:13Z-
dc.date2016-02-25T17:40:13Z-
dc.date2013-10-
dc.date2016-03-30 10:35:44.97925-03-
dc.date.accessioned2019-04-29T15:38:16Z-
dc.date.available2019-04-29T15:38:16Z-
dc.date.issued2013-10-
dc.identifierBonin, Claudio Julio; González, C. E.; Segnorile, Hector Hugo; Zamar, Ricardo César; Evidence for several dipolar quasi-invariants in liquid crystals; American Institute of Physics; Journal of Chemical Physics; 139; 14; 10-2013; 144907-144907-
dc.identifier0021-9606-
dc.identifierhttp://hdl.handle.net/11336/4419-
dc.identifier.urihttp://rodna.bn.gov.ar:8080/jspui/handle/bnmm/298221-
dc.descriptionIn a closed quantum system of N dipole coupled spins with magnetic quantum number I, there are (2I +1)N constants of motion, however, the possibility of observing such quasi-invariants (QIs) in solid-like spin systems in Nuclear Magnetic Resonance (NMR) is not a strictly exact prediction. The aim of this work is to provide experimental evidence of several QIs, in the proton NMR of small spin clusters, besides those already known Zeeman, and dipolar orders (strong and weak). We explore the spin states prepared with the Jeener-Broekaert pulse sequence by analyzing the timedomain signals yielded by this sequence as a function of the preparation times, in a variety of dipolar networks, solids and liquid crystals. We observe that the signals can be explained with two dipolar QIs only within a range of short preparation times. At longer times liquid crystal signals show an echo-like behaviour. We study their multiple quantum coherence content on a basis orthogonal to the z-basis and see that such states involve a significant number of correlated spins. Then we show that the NMR signals within the whole preparation time-scale can only be reconstructed by assuming the occurrence of multiple QIs which we experimentally isolate.-
dc.descriptionFil: Bonin, Claudio Julio. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Física del Litoral; Argentina-
dc.descriptionFil: González, C. E.. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Física "Enrique Gaviola"; Argentina-
dc.descriptionFil: Segnorile, Hector Hugo. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Física "Enrique Gaviola"; Argentina-
dc.descriptionFil: Zamar, Ricardo César. Universidad Nacional de Córdoba. Facultad de Matemática, Astronomía y Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Física "Enrique Gaviola"; Argentina-
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dc.languageeng-
dc.publisherAmerican Institute of Physics-
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1063/1.4823994-
dc.relationinfo:eu-repo/semantics/altIdentifier/url/http://scitation.aip.org/content/aip/journal/jcp/139/14/10.1063/1.4823994-
dc.relationinfo:eu-repo/semantics/altIdentifier/url/http://arxiv.org/abs/1305.1244-
dc.relationinfo:eu-repo/semantics/altIdentifier/issn/0021-9606-
dc.rightsinfo:eu-repo/semantics/openAccess-
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/-
dc.sourcereponame:CONICET Digital (CONICET)-
dc.sourceinstname:Consejo Nacional de Investigaciones Científicas y Técnicas-
dc.sourceinstacron:CONICET-
dc.source.urihttp://hdl.handle.net/11336/4419-
dc.subjectQuasi invariants-
dc.subjectNMR-
dc.subjectLiquid crstals-
dc.subjectQuasi equilibrium-
dc.subjectFísica Atómica, Molecular y Química-
dc.subjectCiencias Físicas-
dc.subjectCIENCIAS NATURALES Y EXACTAS-
dc.titleEvidence for several dipolar quasi-invariants in liquid crystals-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/publishedVersion-
dc.typeinfo:ar-repo/semantics/articulo-
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