Registro completo de metadatos
| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.provenance | CONICET | - |
| dc.creator | Medina Córdoba, Lucrecia Azucena Alcira | - |
| dc.creator | Echeverría, Gustavo Alberto | - |
| dc.creator | Piro, Oscar Enrique | - |
| dc.creator | Gómez, María Inés | - |
| dc.date | 2018-06-25T19:45:29Z | - |
| dc.date | 2018-06-25T19:45:29Z | - |
| dc.date | 2015-06 | - |
| dc.date | 2018-05-14T14:51:59Z | - |
| dc.date.accessioned | 2019-04-29T15:38:32Z | - |
| dc.date.available | 2019-04-29T15:38:32Z | - |
| dc.date.issued | 2015-06 | - |
| dc.identifier | Medina Córdoba, Lucrecia Azucena Alcira; Echeverría, Gustavo Alberto; Piro, Oscar Enrique; Gómez, María Inés; Ammonium, barium hexacyanoferrate(II) trihydrate: Synthesis, crystal structure, thermal decomposition and spectroscopic study; Springer; Journal of Thermal Analysis and Calorimetry; 120; 3; 6-2015; 1827-1834 | - |
| dc.identifier | 1388-6150 | - |
| dc.identifier | http://hdl.handle.net/11336/49979 | - |
| dc.identifier | CONICET Digital | - |
| dc.identifier | CONICET | - |
| dc.identifier.uri | http://rodna.bn.gov.ar:8080/jspui/handle/bnmm/298330 | - |
| dc.description | Abstract The ammonium, barium hexacyanoferrate(II) trihydrate, Ba(NH4)2[Fe(CN)6]·3H2O, has been synthesized for the first time, was characterized by thermogravimetric and differential thermal analysis (TG-DTA), infrared (IR) and Raman spectroscopy and chemical analysis, and its crystal and molecular structures were determined by X-ray diffraction methods. The chemical composition was determined by assaying Ba(II) with EDTA, ammonia nitrogen with Nessler's reagent as indicator and Fe(II) using spectrophotometry with ortho-phenanthroline method. The hydration number was estimated by thermogravimetric analysis. The compound crystallizes in the trigonal R-3c space group. The ferrocyanide anion has an almost perfect octahedral shape with its Fe(II) ion in a crystallographic special position of point symmetry S6 [d(Fe-C) = 1.912(2) Å, d(C-N) = 1.153(3) Å]. The barium, ammonium nitrogen and water oxygen atoms are also at lattice special positions with site symmetries D3, C3 and C2, respectively. The thermal decomposition process was also studied using TG-DTA, and the products of decomposition were identified by IR spectroscopy. It proposes a mechanism of decomposition. | - |
| dc.description | Fil: Medina Córdoba, Lucrecia Azucena Alcira. Universidad Nacional de Tucuman. Facultad de Bioquímica, Química y Farmacia. Instituto de Química Inorganica; Argentina | - |
| dc.description | Fil: Echeverría, Gustavo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina | - |
| dc.description | Fil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina | - |
| dc.description | Fil: Gómez, María Inés. Universidad Nacional de Tucuman. Facultad de Bioquímica, Química y Farmacia. Instituto de Química Inorganica; Argentina | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.language | eng | - |
| dc.publisher | Springer | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/https://dx.doi.org/10.1007/s10973-015-4492-5 | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007%2Fs10973-015-4492-5 | - |
| dc.rights | info:eu-repo/semantics/restrictedAccess | - |
| dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | - |
| dc.source | reponame:CONICET Digital (CONICET) | - |
| dc.source | instname:Consejo Nacional de Investigaciones Científicas y Técnicas | - |
| dc.source | instacron:CONICET | - |
| dc.source.uri | http://hdl.handle.net/11336/49979 | - |
| dc.subject | CRYSTAL STRUCTURE | - |
| dc.subject | FERROCYANIDE | - |
| dc.subject | IR SPECTROSCOPY | - |
| dc.subject | SYNTHESIS | - |
| dc.subject | THERMAL ANALYSIS | - |
| dc.subject | Astronomía | - |
| dc.subject | Ciencias Físicas | - |
| dc.subject | CIENCIAS NATURALES Y EXACTAS | - |
| dc.subject | Otras Ciencias Químicas | - |
| dc.subject | Ciencias Químicas | - |
| dc.subject | CIENCIAS NATURALES Y EXACTAS | - |
| dc.title | Ammonium, barium hexacyanoferrate(II) trihydrate: Synthesis, crystal structure, thermal decomposition and spectroscopic study | - |
| dc.type | info:eu-repo/semantics/article | - |
| dc.type | info:eu-repo/semantics/publishedVersion | - |
| dc.type | info:ar-repo/semantics/articulo | - |
| Aparece en las colecciones: | CONICET | |
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