1. RODNA
  2. CONICET
  3. CONICET
Registro completo de metadatos
Campo DC Valor Lengua/Idioma
dc.provenanceCONICET-
dc.creatorvan Slageren, J.-
dc.creatorMartino, Debora Marcela-
dc.creatorKleverlaan, C.J.-
dc.creatorBussandri, A.-
dc.creatorvan Willigen, H.-
dc.creatorStufkens, D.J.-
dc.date2017-11-07T18:46:05Z-
dc.date2017-11-07T18:46:05Z-
dc.date2000-12-
dc.date2017-11-03T20:26:47Z-
dc.date.accessioned2019-04-29T15:38:38Z-
dc.date.available2019-04-29T15:38:38Z-
dc.date.issued2000-12-
dc.identifiervan Slageren, J.; Martino, Debora Marcela; Kleverlaan, C.J.; Bussandri, A.; van Willigen, H.; et al.; FT-EPR study of methyl radicals photogenerated from [Ru(Me)(SnPh)3(CO)2(iPr-DAB)] and [Pt(Me)4(iPr-DAB)]. An example of a strong excitation wavelength dependent CIDEP effect; American Chemical Society; Journal of Physical Chemistry A; 104; 25; 12-2000; 5969-5973-
dc.identifier1089-5639-
dc.identifierhttp://hdl.handle.net/11336/27762-
dc.identifierCONICET Digital-
dc.identifierCONICET-
dc.identifier.urihttp://rodna.bn.gov.ar:8080/jspui/handle/bnmm/298375-
dc.descriptionThe photoinduced methyl radical formation from the title complexes [Ru(R)(SnPh3)(CO)2(iPr-DAB)] (R ) CH3, CD3; iPr-DAB ) N,N¢-diisopropyl-1,4-diaza-1,3-butadiene) and [Pt(Me)4(iPr-DAB)] was the subject of a detailed time-resolved Fourier transform EPR (FT-EPR) study. The FT-EPR spectra of the radicals show pronounced chemically induced dynamic electron polarization (CIDEP) effects due to the ST0 and ST-1 radical pair mechanisms (RPM). The relative contributions of the two CIDEP mechanisms depend on solvent polarity and viscosity. In the case of the [Ru(R)(SnPh3)(CO)2(iPr-DAB)] complexes, the polarization pattern is also strongly excitation wavelength dependent. This effect is attributed to extremely fast reactions from different thermally nonequilibrated ó-bond-to-ligand charge transfer (SBLCT) excited states.-
dc.descriptionFil: van Slageren, J.. Universiteit Van Amsterdam; Países Bajos-
dc.descriptionFil: Martino, Debora Marcela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina-
dc.descriptionFil: Kleverlaan, C.J.. Universiteit Van Amsterdam; Países Bajos-
dc.descriptionFil: Bussandri, A.. University of Massachusetts at Boston; Estados Unidos-
dc.descriptionFil: van Willigen, H.. University of Massachusetts at Boston; Estados Unidos-
dc.descriptionFil: Stufkens, D.J.. Universiteit Van Amsterdam; Países Bajos-
dc.formatapplication/pdf-
dc.formatapplication/pdf-
dc.languageeng-
dc.publisherAmerican Chemical Society-
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1021/jp001032b-
dc.rightsinfo:eu-repo/semantics/restrictedAccess-
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/-
dc.sourcereponame:CONICET Digital (CONICET)-
dc.sourceinstname:Consejo Nacional de Investigaciones Científicas y Técnicas-
dc.sourceinstacron:CONICET-
dc.source.urihttp://hdl.handle.net/11336/27762-
dc.subjectOtras Ciencias Químicas-
dc.subjectCiencias Químicas-
dc.subjectCIENCIAS NATURALES Y EXACTAS-
dc.titleFT-EPR study of methyl radicals photogenerated from [Ru(Me)(SnPh)3(CO)2(iPr-DAB)] and [Pt(Me)4(iPr-DAB)]. An example of a strong excitation wavelength dependent CIDEP effect-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/publishedVersion-
dc.typeinfo:ar-repo/semantics/articulo-
Aparece en las colecciones: CONICET

Ficheros en este ítem:
No hay ficheros asociados a este ítem.
Mostrar el registro sencillo del ítem