Registro completo de metadatos
| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.provenance | CONICET | - |
| dc.creator | Rivela Fretes, Cynthia Beatriz | - |
| dc.creator | Gibilisco, Rodrigo Gastón | - |
| dc.creator | Teruel, Mariano Andres | - |
| dc.date | 2018-03-23T18:28:43Z | - |
| dc.date | 2018-03-23T18:28:43Z | - |
| dc.date | 2015-07 | - |
| dc.date | 2018-03-22T13:04:03Z | - |
| dc.date.accessioned | 2019-04-29T15:38:55Z | - |
| dc.date.available | 2019-04-29T15:38:55Z | - |
| dc.date.issued | 2015-07 | - |
| dc.identifier | Rivela Fretes, Cynthia Beatriz; Gibilisco, Rodrigo Gastón; Teruel, Mariano Andres; Gas-phase oxidation of CH2 = C(CH3)CH2Cl initiated by OH radicals and Cl atoms: Kinetics and fate of the alcoxy radical formed; John Wiley & Sons Ltd; Journal Of Physical Organic Chemistry; 28; 7; 7-2015; 480-484 | - |
| dc.identifier | 0894-3230 | - |
| dc.identifier | http://hdl.handle.net/11336/39819 | - |
| dc.identifier | CONICET Digital | - |
| dc.identifier | CONICET | - |
| dc.identifier.uri | http://rodna.bn.gov.ar:8080/jspui/handle/bnmm/298494 | - |
| dc.description | Relative kinetics of the reactions of OH radicals and Cl atoms with 3‐chloro‐2‐methyl‐1‐propene has been studied for the first time at 298 K and 1 atm by GC‐FID. Rate coefficients are found to be (in cm3 molecule−1 s−1): k1 (OH + CH2 = C(CH3)CH2Cl) = (3.23 ± 0.35) × 10−11, k2 (Cl + CH2 = C(CH3)CH2Cl) = (2.10 ± 0.78) × 10−10 with uncertainties representing ± 2σ. Product identification under atmospheric conditions was performed by solid phase microextraction/GC‐MS for OH reaction. Chloropropanone was identified as the main degradation product in accordance with the decomposition of the 1,2‐hydroxy alcoxy radical formed. Additionally, reactivity trends and atmospheric implications are discussed. | - |
| dc.description | Fil: Rivela Fretes, Cynthia Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina | - |
| dc.description | Fil: Gibilisco, Rodrigo Gastón. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina | - |
| dc.description | Fil: Teruel, Mariano Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.language | eng | - |
| dc.publisher | John Wiley & Sons Ltd | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1002/poc.3439 | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/poc.3439 | - |
| dc.rights | info:eu-repo/semantics/restrictedAccess | - |
| dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | - |
| dc.source | reponame:CONICET Digital (CONICET) | - |
| dc.source | instname:Consejo Nacional de Investigaciones Científicas y Técnicas | - |
| dc.source | instacron:CONICET | - |
| dc.source.uri | http://hdl.handle.net/11336/39819 | - |
| dc.subject | ATMOSPHERE | - |
| dc.subject | GAS-PHASE MECHANISMS | - |
| dc.subject | RELATIVE KINETICS | - |
| dc.subject | VOCS DEGRADATION | - |
| dc.subject | Meteorología y Ciencias Atmosféricas | - |
| dc.subject | Ciencias de la Tierra y relacionadas con el Medio Ambiente | - |
| dc.subject | CIENCIAS NATURALES Y EXACTAS | - |
| dc.title | Gas-phase oxidation of CH2 = C(CH3)CH2Cl initiated by OH radicals and Cl atoms: Kinetics and fate of the alcoxy radical formed | - |
| dc.type | info:eu-repo/semantics/article | - |
| dc.type | info:eu-repo/semantics/publishedVersion | - |
| dc.type | info:ar-repo/semantics/articulo | - |
| Aparece en las colecciones: | CONICET | |
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