Registro completo de metadatos
| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.provenance | CONICET | - |
| dc.creator | Cobos, Carlos Jorge | - |
| dc.creator | Croce, Adela Ester | - |
| dc.date | 2018-06-15T14:58:47Z | - |
| dc.date | 2018-06-15T14:58:47Z | - |
| dc.date | 2015-10 | - |
| dc.date | 2018-06-14T19:07:08Z | - |
| dc.date.accessioned | 2019-04-29T15:39:02Z | - |
| dc.date.available | 2019-04-29T15:39:02Z | - |
| dc.date.issued | 2015-10 | - |
| dc.identifier | Cobos, Carlos Jorge; Croce, Adela Ester; Theoretical Kinetics Study of the Reactions Forming the ClCO Radical Cycle in the Middle Atmosphere of Venus; Oldenbourg Verlag; Zeitschrift für Physikalische Chemie; 229; 10-12; 10-2015; 1541-1559 | - |
| dc.identifier | 0942-9352 | - |
| dc.identifier | http://hdl.handle.net/11336/48777 | - |
| dc.identifier | CONICET Digital | - |
| dc.identifier | CONICET | - |
| dc.identifier.uri | http://rodna.bn.gov.ar:8080/jspui/handle/bnmm/298549 | - |
| dc.description | A quantum-chemistry and kinetics study of key chemical reactions involved in the ClCO radical cycle of the Venus atmosphere: Cl + CO + M → ClCO + M (1); ClCO + O2 + M → ClC(O)OO + M (2) and ClC(O)OO + Cl → CO2 + ClO + Cl (3) (M = CO2), has been performed at 150-300 K. Unimolecular reaction rate theories on potential energy features derived at the G4//B3LYP/6-311+G(3df) ab initio composite level were employed. Limiting low pressure rate coefficients calculated for Reaction (1) are in good agreement with recommended experimental values. The present results validate rate coefficient values measured for Reaction (2) over relevant strato-mesosphere Venusian conditions. Rate coefficients calculated by the SACM/CT for Reaction (3) are given by k3 = 2.5 × 10-11 (T/300)0.5 cm3 molecule-1 s-1. In the absence of experimental data, these values provide the first reliable prediction for k3. | - |
| dc.description | Fil: Cobos, Carlos Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina | - |
| dc.description | Fil: Croce, Adela Ester. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.language | eng | - |
| dc.publisher | Oldenbourg Verlag | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1515/zpch-2015-0608 | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/url/https://www.degruyter.com/view/j/zpch.2015.229.issue-10-12/zpch-2015-0608/zpch-2015-0608.xml | - |
| dc.rights | info:eu-repo/semantics/restrictedAccess | - |
| dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | - |
| dc.source | reponame:CONICET Digital (CONICET) | - |
| dc.source | instname:Consejo Nacional de Investigaciones Científicas y Técnicas | - |
| dc.source | instacron:CONICET | - |
| dc.source.uri | http://hdl.handle.net/11336/48777 | - |
| dc.subject | AB INITIO CALCULATIONS | - |
| dc.subject | CLCO CYCLE | - |
| dc.subject | SACM/CT CALCULATIONS | - |
| dc.subject | VENUS ATMOSPHERIC CHEMISTRY | - |
| dc.subject | Otras Ciencias Químicas | - |
| dc.subject | Ciencias Químicas | - |
| dc.subject | CIENCIAS NATURALES Y EXACTAS | - |
| dc.title | Theoretical Kinetics Study of the Reactions Forming the ClCO Radical Cycle in the Middle Atmosphere of Venus | - |
| dc.type | info:eu-repo/semantics/article | - |
| dc.type | info:eu-repo/semantics/publishedVersion | - |
| dc.type | info:ar-repo/semantics/articulo | - |
| Aparece en las colecciones: | CONICET | |
Ficheros en este ítem:
No hay ficheros asociados a este ítem.