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| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.provenance | CONICET | - |
| dc.creator | Pagani, María Ayelén | - |
| dc.creator | Baltanas, Miguel Angel | - |
| dc.date | 2017-03-09T17:40:26Z | - |
| dc.date | 2017-03-09T17:40:26Z | - |
| dc.date | 2009-10-14 | - |
| dc.date | 2017-03-01T17:48:37Z | - |
| dc.date.accessioned | 2019-04-29T15:39:13Z | - |
| dc.date.available | 2019-04-29T15:39:13Z | - |
| dc.date.issued | 2009-10-14 | - |
| dc.identifier | Pagani, María Ayelén; Baltanas, Miguel Angel; Production of natural antioxidants from vegetable oil deodorizer distillates: Effect of catalytic hydrogenation; Elsevier; Bioresource Technology; 101; 14-10-2009; 1369-1376 | - |
| dc.identifier | 0960-8524 | - |
| dc.identifier | http://hdl.handle.net/11336/13669 | - |
| dc.identifier.uri | http://rodna.bn.gov.ar:8080/jspui/handle/bnmm/298631 | - |
| dc.description | Natural tocopherols are one of the main types of antioxidants found in living creatures, but they also have other critical biological functions. The biopotency of natural (+)alfa-tocopherol (RRR) is 36% higher than that of the synthetic racemic mixture and 300% higher than the SRR stereoisomer. Vegetable oil deodorizer distillates (DD) are an excellent source of natural tocopherols. Catalytic hydrogenation of DD preconcentrates has been suggested as a feasible route for recovery of tocopherols in high yield. However, it is important to know whether the hydrogenation operation, as applied to these tocopherol-rich mixtures, is capable of preserving the chiral (RRR) character, which is critical to its biopotency.(+)alfa-tocopherol enriched sunflower oil and methyl stearate, as well as sunflower oil DD, were fully hydrogenated using commercial Ni and Pd catalysts (120?180 C; 20?60 psig). Products were analyzed by chiral HPLC. Results show that the desired chiral configuration (RRR) is fully retained. Thus, the hydrogenation route can be safely considered as a valid alternative for increasing the efficiency of tocopherol recovery processes from DDs while preserving their natural characteristics. | - |
| dc.description | Fil: Pagani, María Ayelén. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina | - |
| dc.description | Fil: Baltanas, Miguel Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.language | eng | - |
| dc.publisher | Elsevier | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.biortech.2009.09.068 | - |
| dc.rights | info:eu-repo/semantics/restrictedAccess | - |
| dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | - |
| dc.source | reponame:CONICET Digital (CONICET) | - |
| dc.source | instname:Consejo Nacional de Investigaciones Científicas y Técnicas | - |
| dc.source | instacron:CONICET | - |
| dc.source.uri | http://hdl.handle.net/11336/13669 | - |
| dc.subject | NATURAL TOCOPHEROLS | - |
| dc.subject | DEODORIZER DISTILLATES | - |
| dc.subject | CATALYTIC HYDROGENATION | - |
| dc.subject | Otras Ciencias Químicas | - |
| dc.subject | Ciencias Químicas | - |
| dc.subject | CIENCIAS NATURALES Y EXACTAS | - |
| dc.title | Production of natural antioxidants from vegetable oil deodorizer distillates: Effect of catalytic hydrogenation | - |
| dc.type | info:eu-repo/semantics/article | - |
| dc.type | info:eu-repo/semantics/publishedVersion | - |
| dc.type | info:ar-repo/semantics/articulo | - |
| Aparece en las colecciones: | CONICET | |
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