Registro completo de metadatos
| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.provenance | CONICET | - |
| dc.creator | Balbinot, L. | - |
| dc.creator | Schuchardt, U. | - |
| dc.creator | Vera, Carlos Roman | - |
| dc.creator | Sepúlveda, Juan | - |
| dc.date | 2018-11-27T14:55:35Z | - |
| dc.date | 2018-11-27T14:55:35Z | - |
| dc.date | 2008-05 | - |
| dc.date | 2018-11-22T14:25:01Z | - |
| dc.date.accessioned | 2019-04-29T15:39:21Z | - |
| dc.date.available | 2019-04-29T15:39:21Z | - |
| dc.date.issued | 2008-05 | - |
| dc.identifier | Balbinot, L.; Schuchardt, U.; Vera, Carlos Roman; Sepúlveda, Juan; Oxidation of cyclohexanol to epsilon-caprolactone with aqueous hydrogen peroxide on H3PW12O40 and Cs2.5H0.5PW12O40; Elsevier Science; Catalysis Communications; 9; 9; 5-2008; 1878-1881 | - |
| dc.identifier | 1566-7367 | - |
| dc.identifier | http://hdl.handle.net/11336/65307 | - |
| dc.identifier | CONICET Digital | - |
| dc.identifier | CONICET | - |
| dc.identifier.uri | http://rodna.bn.gov.ar:8080/jspui/handle/bnmm/298692 | - |
| dc.description | Liquid phase cyclohexanol catalytic oxidation to cyclohexanone and epsilon(ε)-caprolactone were studied using aqueous hydrogen peroxide as oxidant and H3PW12O40 (HPA) and H0.5Cs2.5PW12O40 (Cs-salt) as catalysts. The hydrophobic and insoluble Cs-salt showed the highest activity (per unit catalytic weight and turnover number) and selectivity to (ε)-caprolactone. The ultrafine Cs-salt crystallites could be filtrated and recycled. Solvent effects on the activity and selectivity and the rate of peroxide decomposition were assessed and they were correlated to their polarity and protic/aprotic nature. When employing acetonitrile at 90 °C the highest activity and selectivity were achieved and also the lowest rate of hydrogen peroxide decomposition. | - |
| dc.description | Fil: Balbinot, L.. Universidade Estadual de Campinas; Brasil | - |
| dc.description | Fil: Schuchardt, U.. Universidade Estadual de Campinas; Brasil | - |
| dc.description | Fil: Vera, Carlos Roman. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina | - |
| dc.description | Fil: Sepúlveda, Juan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.language | eng | - |
| dc.publisher | Elsevier Science | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.catcom.2008.03.006 | - |
| dc.rights | info:eu-repo/semantics/restrictedAccess | - |
| dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | - |
| dc.source | reponame:CONICET Digital (CONICET) | - |
| dc.source | instname:Consejo Nacional de Investigaciones Científicas y Técnicas | - |
| dc.source | instacron:CONICET | - |
| dc.source.uri | http://hdl.handle.net/11336/65307 | - |
| dc.subject | cyclohexanol | - |
| dc.subject | caprolactone | - |
| dc.subject | heteropolyacid | - |
| dc.subject | Ingeniería Medioambiental y Geológica, Geotécnicas | - |
| dc.subject | Ingeniería del Medio Ambiente | - |
| dc.subject | INGENIERÍAS Y TECNOLOGÍAS | - |
| dc.title | Oxidation of cyclohexanol to epsilon-caprolactone with aqueous hydrogen peroxide on H3PW12O40 and Cs2.5H0.5PW12O40 | - |
| dc.type | info:eu-repo/semantics/article | - |
| dc.type | info:eu-repo/semantics/publishedVersion | - |
| dc.type | info:ar-repo/semantics/articulo | - |
| Aparece en las colecciones: | CONICET | |
Ficheros en este ítem:
No hay ficheros asociados a este ítem.