Registro completo de metadatos
| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.creator | Palermo, Valeria | - |
| dc.creator | Villabrille, Paula Isabel | - |
| dc.creator | Vazquez, Patricia Graciela | - |
| dc.creator | Caceres, Carmen Victoria | - |
| dc.creator | Tundo, Pietro | - |
| dc.creator | Romanelli, Gustavo Pablo | - |
| dc.date | 2016-03-21T15:56:57Z | - |
| dc.date | 2016-03-21T15:56:57Z | - |
| dc.date | 2013-11 | - |
| dc.date | 2016-03-30 10:35:44.97925-03 | - |
| dc.date.accessioned | 2019-04-29T15:39:40Z | - |
| dc.date.available | 2019-04-29T15:39:40Z | - |
| dc.date.issued | 2013-11 | - |
| dc.identifier | Palermo, Valeria; Villabrille, Paula Isabel; Vazquez, Patricia Graciela; Caceres, Carmen Victoria; Tundo, Pietro; et al.; Role of vanadium and pyridine in heteropolycompounds for selective oxidation of alcohols with hydrogen peroxide; Springer; Journal of Chemical Science; 125; 6; 11-2013; 1375-1383 | - |
| dc.identifier | 0974-3626 | - |
| dc.identifier | http://hdl.handle.net/11336/4875 | - |
| dc.identifier | 0973-7103 | - |
| dc.identifier.uri | http://rodna.bn.gov.ar:8080/jspui/handle/bnmm/298837 | - |
| dc.description | This study describes the application of heteropolyacids H3PMo12O40,H4SiMo12O40, H4PMo11VO40, H5PMo10V2O40, H9PMo6V6O40, and a hybrid pyridine-modified heteropolyacid with Keggin structure for selective oxidation of alcohols to ketones or aldehydes using aqueous hydrogen peroxide and acetonitrile as solvent. Performance of these different catalysts in 1 phenylethanol oxidation was studied. Influence of reaction temperature, amount of catalyst and hydrogen peroxide and reaction time on the yield of acetophenone was investigated to obtain optimal reaction conditions. Oxidation ability of the catalyst depended on the number of vanadium atoms present in the Keggin ion and to a lesser extent on pyridine substitution in the Keggin secondary structure. In order to explore the applicability of the method for selective oxidation of alcohols to ketones or aldehydes, various alcohols were investigated according to the general procedure using hybrid pyridine-modified heteropolyacid. | - |
| dc.description | Fil: Palermo, Valeria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina | - |
| dc.description | Fil: Villabrille, Paula Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales; Argentina | - |
| dc.description | Fil: Vazquez, Patricia Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina | - |
| dc.description | Fil: Caceres, Carmen Victoria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina | - |
| dc.description | Fil: Tundo, Pietro. Universita Ca Foscari Venezia. Dipartimento di scienze ambientali, informatica e statistica; Italia | - |
| dc.description | Fil: Romanelli, Gustavo Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales; Argentina | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.language | eng | - |
| dc.publisher | Springer | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/url/http://link.springer.com/article/10.1007%2Fs12039-013-0523-6 | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/10.1007/s12039-013-0523-6 | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1007/s12039-013-0523-6 | - |
| dc.rights | info:eu-repo/semantics/restrictedAccess | - |
| dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | - |
| dc.source | reponame:CONICET Digital (CONICET) | - |
| dc.source | instname:Consejo Nacional de Investigaciones Científicas y Técnicas | - |
| dc.source | instacron:CONICET | - |
| dc.source.uri | http://hdl.handle.net/11336/33354 | - |
| dc.subject | OXIDATION REACTION | - |
| dc.subject | ALCOHOL OXIDATION | - |
| dc.subject | VANADIUM-SUBSTITUTED HETEROPOLYACIDS | - |
| dc.subject | PYRIDINIUM HETEROPOLYACID SALT | - |
| dc.subject | Química Orgánica | - |
| dc.subject | Ciencias Químicas | - |
| dc.subject | CIENCIAS NATURALES Y EXACTAS | - |
| dc.title | Role of vanadium and pyridine in heteropolycompounds for selective oxidation of alcohols with hydrogen peroxide | - |
| dc.type | info:eu-repo/semantics/article | - |
| dc.type | info:eu-repo/semantics/publishedVersion | - |
| dc.type | info:ar-repo/semantics/articulo | - |
| Aparece en las colecciones: | CONICET | |
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