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dc.creatorDíez, Alejandra-
dc.creatorSchmidt, Rainer-
dc.creatorSagua, Aurora Estela-
dc.creatorFrechero, Marisa Alejandra-
dc.creatorMatesanz, Emilio-
dc.creatorLeon, Carlos-
dc.creatorMorán Emilio, E.-
dc.date2018-11-09T14:29:43Z-
dc.date2018-11-09T14:29:43Z-
dc.date2010-09-
dc.date2018-11-05T19:09:40Z-
dc.date.accessioned2019-04-29T15:39:52Z-
dc.date.available2019-04-29T15:39:52Z-
dc.date.issued2010-09-
dc.identifierDíez, Alejandra; Schmidt, Rainer; Sagua, Aurora Estela; Frechero, Marisa Alejandra; Matesanz, Emilio; et al.; Structure and physical properties of nickel manganite NiMn2O4 obtained from nickel permanganate precursor; Elsevier; Journal of the European Ceramic Society; 30; 12; 9-2010; 2617-2624-
dc.identifier0955-2219-
dc.identifierhttp://hdl.handle.net/11336/64066-
dc.identifierCONICET Digital-
dc.identifierCONICET-
dc.identifier.urihttp://rodna.bn.gov.ar:8080/jspui/handle/bnmm/298928-
dc.descriptionIn this paper we present the structural, magnetic and dielectric properties of ceramic nickel manganite NiMn2O4+δ produced by using nickel permanganate Ni(MnO4)2xH2O as a precursor. We have characterized the NiMn2O4+δ stoichiometry using quantitative energy-dispersive analysis of X-rays and thermal gravimetry under reducing conditions. Increased oxygen and Mn4+ contents were detected. X-ray diffraction and Rietveld refinement of X-ray data were carried out. Temperature dependent magnetization measurements were performed and the ferri-magnetic transition was identified at ≈100K. The ferri-magnetic moment was found to be ≈1μB and hysteretic magnetization vs applied field curves were obtained. Dielectric properties were measured using impedance spectroscopy. Two dielectric relaxation processes were detected, which were associated with grain boundary and bulk contributions. The Arrhenius plots of resistivity and the temperature dependent dielectric permittivity were obtained for the two relaxations by means of an equivalent circuit model based on a series of two parallel RC elements. © 2010 Elsevier Ltd.-
dc.descriptionFil: Díez, Alejandra. Universidad Nacional del Sur. Departamento de Química; Argentina-
dc.descriptionFil: Schmidt, Rainer. Universidad Complutense de Madrid; España-
dc.descriptionFil: Sagua, Aurora Estela. Universidad Nacional del Sur. Departamento de Química; Argentina-
dc.descriptionFil: Frechero, Marisa Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina-
dc.descriptionFil: Matesanz, Emilio. Universidad Complutense de Madrid; España-
dc.descriptionFil: Leon, Carlos. Universidad Complutense de Madrid; España-
dc.descriptionFil: Morán Emilio, E.. Universidad Complutense de Madrid; España-
dc.formatapplication/pdf-
dc.formatapplication/pdf-
dc.formatapplication/pdf-
dc.languageeng-
dc.publisherElsevier-
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/https://dx.doi.org/10.1016/j.jeurceramsoc.2010.04.032-
dc.relationinfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0955221910002037-
dc.rightsinfo:eu-repo/semantics/restrictedAccess-
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/-
dc.sourcereponame:CONICET Digital (CONICET)-
dc.sourceinstname:Consejo Nacional de Investigaciones Científicas y Técnicas-
dc.sourceinstacron:CONICET-
dc.source.urihttp://hdl.handle.net/11336/24395-
dc.subjectB. X-RAY METHODS-
dc.subjectC. CHEMICAL PROPERTIES-
dc.subjectC. DIELECTRIC PROPERTIES. E. THERMISTORS-
dc.subjectC. MAGNETIC PROPERTIES-
dc.subjectOtras Ciencias Químicas-
dc.subjectCiencias Químicas-
dc.subjectCIENCIAS NATURALES Y EXACTAS-
dc.titleStructure and physical properties of nickel manganite NiMn2O4 obtained from nickel permanganate precursor-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/publishedVersion-
dc.typeinfo:ar-repo/semantics/articulo-
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