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dc.creatorFernández, Pablo S.-
dc.creatorMartins, Cauê A.-
dc.creatorAngelucci, Camilo A.-
dc.creatorGomes, Janaina F.-
dc.creatorCamara, Giuseppe A.-
dc.creatorMartins, María Elisa-
dc.creatorTremiliosi‐Filho, Germano-
dc.date2016-04-15T14:29:25Z-
dc.date2016-04-15T14:29:25Z-
dc.date2015-02-
dc.date2016-05-06 15:52:43.262787-03-
dc.date.accessioned2019-04-29T15:40:36Z-
dc.date.available2019-04-29T15:40:36Z-
dc.date.issued2016-04-15T14:29:25Z-
dc.date.issued2016-04-15T14:29:25Z-
dc.date.issued2015-02-
dc.date.issued2016-05-06 15:52:43.262787-03-
dc.identifierFernández, Pablo S.; Martins, Cauê A.; Angelucci, Camilo A.; Gomes, Janaina F.; Camara, Giuseppe A.; et al.; Evidence of independent glycerol electrooxidation behavior on different ordered domains of polycrystalline Pt; Wiley; ChemElectroChem; 2; 2; 2-2015; 263-268-
dc.identifier2196-0216-
dc.identifierhttp://hdl.handle.net/11336/5218-
dc.identifier.urihttp://rodna.bn.gov.ar:8080/jspui/handle/bnmm/299242-
dc.descriptionWe investigate the electrooxidation of glycerol (GlOH) on polycrystalline Pt. The results obtained in the presence of GlOH were compared with those of fresh and disturbed low-index Pt single crystals [(111), (100) and (110)]. Monitoring of the oxidation currents of GlOH by cyclic voltammetry on the different surfaces revealed that the electrooxidation of GlOH is highly sensitive to the order of the polycrystalline Pt atoms. Interestingly, after being disturbed by the application of voltammetric cycles, the combined responses of the disordered single crystals become similar to that of polycrystalline Pt. The changes in the current values associated with the specific potentials at which each oxidation peak takes place suggest that different ordered domains of Pt oxidize GlOH independently. This simple approach can clearly assist in our understanding of the effect of the order of surface atoms in a given reaction, not only in electrochemical reactions.-
dc.descriptionFil: Fernández, Pablo S.. Universidade Estadual de Campinas; Brasil. Universidade de São Paulo. Instituto de Química de São Carlos; Brasil-
dc.descriptionFil: Martins, Cauê A.. Universidade Federal Grande Dourados; Brasil-
dc.descriptionFil: Angelucci, Camilo A.. Universidade Federal ABC- Santo André; Brasil-
dc.descriptionFil: Gomes, Janaina F.. Universidade Federal Do Sao Carlos. Departamento de Engenharia Quimica; Brasil-
dc.descriptionFil: Camara, Giuseppe A.. Universidade Federal Do Mato Grosso Do Sul; Brasil-
dc.descriptionFil: Martins, María Elisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de la Plata; Argentina-
dc.descriptionFil: Tremiliosi‐Filho, Germano. Universidade de Sao Paulo. Instituto Química de Sao Carlos; Brasil-
dc.formatapplication/pdf-
dc.formatapplication/pdf-
dc.languageeng-
dc.publisherWiley-
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/10.1002/celc.201402291-
dc.relationinfo:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/celc.201402291/full-
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1002/celc.201402291-
dc.rightsinfo:eu-repo/semantics/restrictedAccess-
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/-
dc.sourcereponame:CONICET Digital (CONICET)-
dc.sourceinstname:Consejo Nacional de Investigaciones Científicas y Técnicas-
dc.sourceinstacron:CONICET-
dc.subjectALCOHOLS-
dc.subjectBIOFUELS-
dc.subjectELECTROOXIDATION-
dc.subjectPLATINUM-
dc.subjectSURFACE CHEMISTRY-
dc.subjectFísico-Química, Ciencia de los Polímeros, Electroquímica-
dc.subjectCiencias Químicas-
dc.subjectCIENCIAS NATURALES Y EXACTAS-
dc.titleEvidence of independent glycerol electrooxidation behavior on different ordered domains of polycrystalline Pt-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/publishedVersion-
dc.typeinfo:ar-repo/semantics/articulo-
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