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dc.creatorBraun, Fernando-
dc.creatorTarditi, Ana Maria-
dc.creatorCornaglia, Laura Maria-
dc.date2018-07-23T19:08:39Z-
dc.date2018-07-23T19:08:39Z-
dc.date2011-10-
dc.date2018-07-20T14:19:01Z-
dc.date.accessioned2019-04-29T15:41:01Z-
dc.date.available2019-04-29T15:41:01Z-
dc.date.issued2018-07-23T19:08:39Z-
dc.date.issued2018-07-23T19:08:39Z-
dc.date.issued2011-10-
dc.date.issued2018-07-20T14:19:01Z-
dc.identifierBraun, Fernando; Tarditi, Ana Maria; Cornaglia, Laura Maria; Optimization and characterization of electroless co-deposited PdRu membranes: Effect of the plating variables on morphology; Elsevier Science; Journal of Membrane Science; 382; 1-2; 10-2011; 252-261-
dc.identifier0376-7388-
dc.identifierhttp://hdl.handle.net/11336/52874-
dc.identifierCONICET Digital-
dc.identifierCONICET-
dc.identifier.urihttp://rodna.bn.gov.ar:8080/jspui/handle/bnmm/299429-
dc.descriptionPdRu films were successfully synthesized on top of non-porous stainless steel supports by electroless co-deposition. The effect of synthesis variables on morphology, substrate adherence, bulk and surface composition was studied. The microstructure and morphology of the samples were analyzed by X-ray diffraction and scanning electron microscopy. Homogeneous and defect-free PdRu films were obtained employing baths at low pH, moderate to high agitation speeds, high concentration of hydrazine, using EDTA as a stabilizer and temperatures near 50°C. Films characterized by X-ray photoelectron spectroscopy showed Pd segregation after annealing the sample at 400°C in H2 (5%)/Ar in the load-lock chamber of the spectrometer. The optimized conditions were employed to synthesize a PdRu composite membrane on top of a tubular porous stainless steel substrate (0.1μm grade). Hydrogen permeation was measured over a 350-450°C temperature range and a trans-membrane pressure up to 100kPa. The PdRu membrane showed good performance with a hydrogen permeability of 6.5×10-9molm-1s-1Pa-0.5 and a selectivity higher than 1700.-
dc.descriptionFil: Braun, Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina-
dc.descriptionFil: Tarditi, Ana Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina-
dc.descriptionFil: Cornaglia, Laura Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina-
dc.formatapplication/pdf-
dc.formatapplication/pdf-
dc.formatapplication/pdf-
dc.languageeng-
dc.publisherElsevier Science-
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.memsci.2011.08.019-
dc.relationinfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0376738811005965-
dc.rightsinfo:eu-repo/semantics/restrictedAccess-
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/-
dc.sourcereponame:CONICET Digital (CONICET)-
dc.sourceinstname:Consejo Nacional de Investigaciones Científicas y Técnicas-
dc.sourceinstacron:CONICET-
dc.subjectCO-DEPOSITION-
dc.subjectELECTROLESS PLATING-
dc.subjectPDRU MEMBRANE-
dc.subjectOtras Ciencias Químicas-
dc.subjectCiencias Químicas-
dc.subjectCIENCIAS NATURALES Y EXACTAS-
dc.titleOptimization and characterization of electroless co-deposited PdRu membranes: Effect of the plating variables on morphology-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/publishedVersion-
dc.typeinfo:ar-repo/semantics/articulo-
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