Registro completo de metadatos
| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.creator | Khan, M. Naveed | - |
| dc.creator | Rovetto, Laura Jorgelina | - |
| dc.creator | Peters, Cor J. | - |
| dc.creator | Sloan, E. Dendy | - |
| dc.creator | Sum, Amadeu K. | - |
| dc.creator | Koh, Carolyn A. | - |
| dc.date | 2018-03-05T15:42:20Z | - |
| dc.date | 2018-03-05T15:42:20Z | - |
| dc.date | 2015-02 | - |
| dc.date | 2018-03-02T14:18:13Z | - |
| dc.date.accessioned | 2019-04-29T15:41:54Z | - |
| dc.date.available | 2019-04-29T15:41:54Z | - |
| dc.date.issued | 2015-02 | - |
| dc.identifier | Khan, M. Naveed; Rovetto, Laura Jorgelina; Peters, Cor J.; Sloan, E. Dendy; Sum, Amadeu K.; et al.; Effect of hydrogen-to-methane concentration ratio on the phase equilibria of quaternary hydrate systems; American Chemical Society; Journal of Chemical and Engineering Data; 60; 2; 2-2015; 418-423 | - |
| dc.identifier | 0021-9568 | - |
| dc.identifier | http://hdl.handle.net/11336/37788 | - |
| dc.identifier | CONICET Digital | - |
| dc.identifier | CONICET | - |
| dc.identifier.uri | http://rodna.bn.gov.ar:8080/jspui/handle/bnmm/299823 | - |
| dc.description | Clathrate hydrates of hydrogen are of specific interest due to their potential ability to store molecular hydrogen. In particular, structure H (sH) hydrate has a higher theoretical storage capacity in comparison with the other two more common hydrate structures (sI and sII). This paper investigates the effect of hydrogen (H2) concentration on the phase equilibria of sH hydrate in a quaternary system of water, methane, hydrogen, and methylcyclohexane. Phase equilibria and cage occupancies of the quaternary system were predicted using the van der Waals and Platteeuw (vdWP) model for different hydrogen/methane ratios ranging from 0 to 7. Model predictions for the quaternary systems were found to be in good agreement with measured experimental data. It was evident from the thermodynamic equilibrium conditions of the quaternary system (MCH + H2O + CH4 + H2) that as the H2 concentration increases (H2:CH4 ratio increased from 0 to 7), higher pressures are required to produce sH hydrates at the same temperature. It was also found that the fractional cage occupancy of CH4 in the small and medium cages of sH hydrate increases with pressure. | - |
| dc.description | Fil: Khan, M. Naveed. Petroleum Institute. Chemical Engineering Department; Emiratos Arabes Unidos. Colorado School of Mines. Chemical & Biological Department. Center for Hydrate Research; Estados Unidos | - |
| dc.description | Fil: Rovetto, Laura Jorgelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (I). Grupo Vinculado al Plapiqui - Investigación y Desarrollo en Tecnología Química; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas, Físicas y Naturales; Argentina | - |
| dc.description | Fil: Peters, Cor J.. Petroleum Institute. Chemical Engineering Department; Emiratos Arabes Unidos | - |
| dc.description | Fil: Sloan, E. Dendy. Colorado School of Mines. Chemical & Biological Department. Center for Hydrate Research; Estados Unidos | - |
| dc.description | Fil: Sum, Amadeu K.. Colorado School of Mines. Chemical & Biological Department. Center for Hydrate Research; Estados Unidos | - |
| dc.description | Fil: Koh, Carolyn A.. Colorado School of Mines. Chemical & Biological Department. Center for Hydrate Research; Estados Unidos | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.language | eng | - |
| dc.publisher | American Chemical Society | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/je500675q | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1021/je500675q | - |
| dc.rights | info:eu-repo/semantics/restrictedAccess | - |
| dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | - |
| dc.source | reponame:CONICET Digital (CONICET) | - |
| dc.source | instname:Consejo Nacional de Investigaciones Científicas y Técnicas | - |
| dc.source | instacron:CONICET | - |
| dc.source.uri | http://hdl.handle.net/11336/64189 | - |
| dc.subject | Gas hydrate | - |
| dc.subject | Structure H | - |
| dc.subject | Hydrogen | - |
| dc.subject | Methane | - |
| dc.subject | Otras Ingeniería Química | - |
| dc.subject | Ingeniería Química | - |
| dc.subject | INGENIERÍAS Y TECNOLOGÍAS | - |
| dc.title | Effect of hydrogen-to-methane concentration ratio on the phase equilibria of quaternary hydrate systems | - |
| dc.type | info:eu-repo/semantics/article | - |
| dc.type | info:eu-repo/semantics/publishedVersion | - |
| dc.type | info:ar-repo/semantics/articulo | - |
| Aparece en las colecciones: | CONICET | |
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