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Campo DC | Valor | Lengua/Idioma |
---|---|---|
dc.creator | Chiappero, Malisa Susana | - |
dc.creator | Argüello, Gustavo Alejandro | - |
dc.creator | Hurley, Michael D. | - |
dc.creator | Wallington, Timothy J. | - |
dc.date | 2019-02-05T15:30:47Z | - |
dc.date | 2019-02-05T15:30:47Z | - |
dc.date | 2010-05 | - |
dc.date | 2019-01-14T15:01:40Z | - |
dc.date.accessioned | 2019-04-29T15:42:14Z | - |
dc.date.available | 2019-04-29T15:42:14Z | - |
dc.date.issued | 2010-05 | - |
dc.identifier | Chiappero, Malisa Susana; Argüello, Gustavo Alejandro; Hurley, Michael D.; Wallington, Timothy J.; Atmospheric Chemistry of n-C6F13CH2CHO: Formation from n-C6F13CH2CH2OH, Kinetics, and Mechanisms of Reactions with Chlorine Atoms and OH Radicals; American Chemical Society; Journal of Physical Chemistry A; 114; 20; 5-2010; 6131-6137 | - |
dc.identifier | 1089-5639 | - |
dc.identifier | http://hdl.handle.net/11336/69406 | - |
dc.identifier | CONICET Digital | - |
dc.identifier | CONICET | - |
dc.identifier.uri | http://rodna.bn.gov.ar:8080/jspui/handle/bnmm/299965 | - |
dc.description | Smog chamber FTIR techniques were used to measure k(Cl + n-C 6F13CH2CHO) = (1.84 ± 0.22) -10 -11, k(Cl + n-C6F13CHO) = (1.75 ± 0.70) - 10-12, and k(OH + n-C6F13CH2CHO) = (2.15 ± 0.26) - 10-12 cm3 molecule-1 s-1 in 700 Torr of N2 or air diluent at 296 ± 2K. The chlorine-atom-initiated oxidation of n-C6F13CH 2CH2OH in air gives n-C6F13CH 2CHO in a molar yield of 99 ± 8%. The atmospheric fate of n-C6F13CH2C(O) radicals is reaction with O 2, while the fate of n-C6F13C(O) radicals is decomposition to give n-C6F13 radicals and CO. The results are discussed with respect to the atmospheric chemistry of fluorinated alcohols and the formation of perfluorocarboxylic acids. | - |
dc.description | Fil: Chiappero, Malisa Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina | - |
dc.description | Fil: Argüello, Gustavo Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina | - |
dc.description | Fil: Hurley, Michael D.. Ford Motor Company; Estados Unidos | - |
dc.description | Fil: Wallington, Timothy J.. Ford Motor Company; Estados Unidos | - |
dc.format | application/pdf | - |
dc.format | application/pdf | - |
dc.language | eng | - |
dc.publisher | American Chemical Society | - |
dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1021/jp101587m | - |
dc.relation | info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/abs/10.1021/jp101587m | - |
dc.rights | info:eu-repo/semantics/restrictedAccess | - |
dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | - |
dc.source | reponame:CONICET Digital (CONICET) | - |
dc.source | instname:Consejo Nacional de Investigaciones Científicas y Técnicas | - |
dc.source | instacron:CONICET | - |
dc.source.uri | http://hdl.handle.net/11336/14634 | - |
dc.subject | fluorotelomer | - |
dc.subject | smog chamber | - |
dc.subject | Atmospheric impact | - |
dc.subject | Otras Ciencias Químicas | - |
dc.subject | Ciencias Químicas | - |
dc.subject | CIENCIAS NATURALES Y EXACTAS | - |
dc.title | Atmospheric Chemistry of n-C6F13CH2CHO: Formation from n-C6F13CH2CH2OH, Kinetics, and Mechanisms of Reactions with Chlorine Atoms and OH Radicals | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/publishedVersion | - |
dc.type | info:ar-repo/semantics/articulo | - |
Aparece en las colecciones: | CONICET |
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