Registro completo de metadatos
| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.creator | Capello, Marcela Carolina | - |
| dc.creator | Broquier , Michel | - |
| dc.creator | Ishiuchi, Shun-Ichi | - |
| dc.creator | Sohn, Woon Y. | - |
| dc.creator | Fujii, Masaaki | - |
| dc.creator | Dedonder-Lardeux, Claude | - |
| dc.creator | Jouvet, Christophe | - |
| dc.creator | Pino, Gustavo Ariel | - |
| dc.date | 2017-12-22T13:09:01Z | - |
| dc.date | 2017-12-22T13:09:01Z | - |
| dc.date | 2014-01 | - |
| dc.date | 2017-12-21T16:26:02Z | - |
| dc.date.accessioned | 2019-04-29T15:43:44Z | - |
| dc.date.available | 2019-04-29T15:43:44Z | - |
| dc.date.issued | 2017-12-22T13:09:01Z | - |
| dc.date.issued | 2017-12-22T13:09:01Z | - |
| dc.date.issued | 2014-01 | - |
| dc.date.issued | 2017-12-21T16:26:02Z | - |
| dc.identifier | Dedonder-Lardeux, Claude; Fujii, Masaaki; Sohn, Woon Y.; Ishiuchi, Shun-Ichi; Broquier , Michel; Capello, Marcela Carolina; et al.; Fast non-radiative decay in o-aminophenol; American Chemical Society; Journal of Physical Chemistry A; 118; 1-2014; 2056-2062 | - |
| dc.identifier | 1089-5639 | - |
| dc.identifier | http://hdl.handle.net/11336/31348 | - |
| dc.identifier | CONICET Digital | - |
| dc.identifier | CONICET | - |
| dc.identifier.uri | http://rodna.bn.gov.ar:8080/jspui/handle/bnmm/300480 | - |
| dc.description | The gas phase structure of 2-aminophenol has been investigated using UV-UV as well as IR-UV hole-burning spectroscopy. The presence of a free OH vibration in the IR spectrum rules out the contribution of the cisisomer, which is expected to have an intramolecular H-bond, to the spectra. The excited state lifetimes of different vibronic levels have been measured with pump probe picosecond experiments and are all very short (35 ± 5) ps as compared to other substituted phenols.The electronic states and active vibrational modes of the cisand transisomers have been calculated with ab initiomethods for comparison with the experimental spectra. The Franck Condon simulation of the spectrum using the calculated ground and excited state frequenciesof the transisomeris in good agreement with the experimental one.The very short excited state lifetime of 2-aminophenol can then be explained by the strong coupling between thetwofirst singlet excited states due to the absence of symmetry, the geometry of the transisomer being strongly non planar in the excited state. | - |
| dc.description | Fil: Capello, Marcela Carolina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina | - |
| dc.description | Fil: Broquier , Michel. Universite Paris Sud; Francia | - |
| dc.description | Fil: Ishiuchi, Shun-Ichi. Tokyo Institute of Technology; Japón | - |
| dc.description | Fil: Sohn, Woon Y.. Tokyo Institute of Technology; Japón | - |
| dc.description | Fil: Fujii, Masaaki. Tokyo Institute of Technology; Japón | - |
| dc.description | Fil: Dedonder-Lardeux, Claude. Aix-Marseille Université; Francia | - |
| dc.description | Fil: Jouvet, Christophe. Aix-Marseille Université; Francia | - |
| dc.description | Fil: Pino, Gustavo Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.language | eng | - |
| dc.publisher | American Chemical Society | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1021/jp411457v | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/10.1021/jp411457v | - |
| dc.rights | info:eu-repo/semantics/restrictedAccess | - |
| dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | - |
| dc.source | reponame:CONICET Digital (CONICET) | - |
| dc.source | instname:Consejo Nacional de Investigaciones Científicas y Técnicas | - |
| dc.source | instacron:CONICET | - |
| dc.subject | excited states | - |
| dc.subject | lifetime | - |
| dc.subject | ortho substituted phenol | - |
| dc.subject | conical intersection | - |
| dc.subject | out-of-planevibration | - |
| dc.subject | Otras Ciencias Químicas | - |
| dc.subject | Ciencias Químicas | - |
| dc.subject | CIENCIAS NATURALES Y EXACTAS | - |
| dc.title | Fast non-radiative decay in o-aminophenol | - |
| dc.type | info:eu-repo/semantics/article | - |
| dc.type | info:eu-repo/semantics/publishedVersion | - |
| dc.type | info:ar-repo/semantics/articulo | - |
| Aparece en las colecciones: | CONICET | |
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