Registro completo de metadatos
| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.provenance | CONICET | - |
| dc.creator | Diniz, Paulo Henrique Gonçalves Dias | - |
| dc.creator | Pistonesi, Marcelo Fabian | - |
| dc.creator | Araújo, Mario César Ugulino de | - |
| dc.creator | Fernández Band, Beatriz Susana | - |
| dc.date | 2016-04-28T14:39:15Z | - |
| dc.date | 2016-04-28T14:39:15Z | - |
| dc.date | 2013-04 | - |
| dc.date | 2016-05-06 15:52:43.262787-03 | - |
| dc.date.accessioned | 2019-04-29T15:44:23Z | - |
| dc.date.available | 2019-04-29T15:44:23Z | - |
| dc.date.issued | 2016-04-28T14:39:15Z | - |
| dc.date.issued | 2016-04-28T14:39:15Z | - |
| dc.date.issued | 2013-04 | - |
| dc.date.issued | 2016-05-06 15:52:43.262787-03 | - |
| dc.identifier | Diniz, Paulo Henrique Gonçalves Dias ; Pistonesi, Marcelo Fabian; Araújo, Mario César Ugulino de ; Fernández Band, Beatriz Susana; Eco-friendly sonoluminescent determination of free glycerol in biodiesel samples.; Elsevier; Talanta; 114; 4-2013; 38-42 | - |
| dc.identifier | 0039-9140 | - |
| dc.identifier | http://hdl.handle.net/11336/5417 | - |
| dc.identifier.uri | http://rodna.bn.gov.ar:8080/jspui/handle/bnmm/300771 | - |
| dc.description | This paper proposes a flow-batch methodology for the determination of free glycerol in biodiesel that is notably eco-friendly, since non-chemical reagents are used. Deionized water (the solvent) was used alone for glycerol (sample) extractions from the biodiesel. The same water was used to generate water-cavitation sonoluminescence signals, which were modulated by the quenching effect associated with the amount of extracted glycerol. The necessarily reproducible signal generation was achieved by using a simple and inexpensive piezoelectric device. A linear response was observed for glycerol within the 0.001–100 mg/L range, equivalent to 0.004–400 mg/kg free glycerol in biodiesel. The lowest measurable concentration of free glycerol was estimated at 1.0 µg/L. The selectivity of the proposed method was confirmed by comparing the shape and retention of both real and calibration samples to standard solution chromatograms, presenting no peaks other than glycerol. All samples (after extraction) are greatly diluted; this minimizes (toward non-detectability) potential interference effects. The methodology was successfully applied to biodiesel analysis at a high sampling rate, with neither reagent nor solvent (other than water), and with minimum waste generation. The results agreed with the reference method (ASTM D6584-07), at a 95% confidence level. | - |
| dc.description | Fil: Diniz, Paulo Henrique Gonçalves Dias . Universidade Federal da Paraíba. Departamento de Química; Brasil | - |
| dc.description | Fil: Pistonesi, Marcelo Fabian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; Argentina | - |
| dc.description | Fil: Araújo, Mario César Ugulino de . Universidade Federal da Paraíba. Departamento de Química; Brasil | - |
| dc.description | Fil: Fernández Band, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; Argentina | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.language | eng | - |
| dc.publisher | Elsevier | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0039914013002919 | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/10.1016/j.talanta.2013.04.009 | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.talanta.2013.04.009 | - |
| dc.rights | info:eu-repo/semantics/restrictedAccess | - |
| dc.rights | https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ | - |
| dc.source | reponame:CONICET Digital (CONICET) | - |
| dc.source | instname:Consejo Nacional de Investigaciones Científicas y Técnicas | - |
| dc.source | instacron:CONICET | - |
| dc.source.uri | http://hdl.handle.net/11336/5417 | - |
| dc.subject | FLOW BATCH | - |
| dc.subject | GLYCEROL | - |
| dc.subject | ONLINE EXTRACTION | - |
| dc.subject | SONOLUMINESCENCE | - |
| dc.subject | Química Analítica | - |
| dc.subject | Ciencias Químicas | - |
| dc.subject | CIENCIAS NATURALES Y EXACTAS | - |
| dc.title | Eco-friendly sonoluminescent determination of free glycerol in biodiesel samples. | - |
| dc.type | info:eu-repo/semantics/article | - |
| dc.type | info:eu-repo/semantics/publishedVersion | - |
| dc.type | info:ar-repo/semantics/articulo | - |
| Aparece en las colecciones: | CONICET | |
Ficheros en este ítem:
No hay ficheros asociados a este ítem.