Registro completo de metadatos
| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.provenance | CONICET | - |
| dc.creator | Berasategui, Matias | - |
| dc.creator | Argüello, Gustavo Alejandro | - |
| dc.creator | Burgos Paci, Maximiliano Alberto | - |
| dc.date | 2018-11-13T18:09:41Z | - |
| dc.date | 2018-11-13T18:09:41Z | - |
| dc.date | 2017-10-20 | - |
| dc.date | 2018-10-22T18:58:56Z | - |
| dc.date.accessioned | 2019-04-29T15:44:33Z | - |
| dc.date.available | 2019-04-29T15:44:33Z | - |
| dc.date.issued | 2017-10-20 | - |
| dc.identifier | Berasategui, Matias; Argüello, Gustavo Alejandro; Burgos Paci, Maximiliano Alberto; Reaction of methyl fluoroformyl peroxycarbonate (FC(O)OOC(O)OCH3) with Cl atoms: Formation of hydro-chlorofluoro-peroxides; American Chemical Society; Journal of Physical Chemistry A; 121; 40; 20-10-2017; 7469-7476 | - |
| dc.identifier | 1089-5639 | - |
| dc.identifier | http://hdl.handle.net/11336/64347 | - |
| dc.identifier | 1520-5215 | - |
| dc.identifier | CONICET Digital | - |
| dc.identifier | CONICET | - |
| dc.identifier.uri | http://rodna.bn.gov.ar:8080/jspui/handle/bnmm/300843 | - |
| dc.description | The products following Cl atom initiated reactions of FC(O)OOC(O)OCH3 in 50-760 Torr of N2 at 296 K were investigated using FTIR. Reaction of Cl atoms with methyl fluoroformyl peroxycarbonate proceeds mainly via attack at the methyl group, forming FC(O)OOC(O)OCH2 • radicals. Further reaction of this kind of radical with Cl2 forms three new compounds: FC(O)OOC(O)OCH2Cl, FC(O)OOC(O)OCHCl2, and FC(O)OOC(O)OCCl3, whose existence was characterized experimentally by FTIR spectroscopy assisted by ab initio calculations at the B3LYP/6-31++G(d,p) level. Relative rate techniques were used to measure k(Cl+FC(O)OOC(O)OCH3) = (4.0 ± 0.4) × 10-14 cm3 molecule-1 s-1 and k(Cl+FC(O)OOC(O)OCH2Cl) = (3.2 ± 0.3) × 10-14 cm3 molecule-1 s-1. When the reaction is run in the presence of oxygen, the paths giving chlorinated peroxide formation are suppressed, and oxidation to (mainly) CO2 and HCl takes place through highly oxidized intermediates with lifetimes long enough to be detected by FTIR spectroscopy. | - |
| dc.description | Fil: Berasategui, Matias. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina | - |
| dc.description | Fil: Argüello, Gustavo Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina | - |
| dc.description | Fil: Burgos Paci, Maximiliano Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.language | eng | - |
| dc.publisher | American Chemical Society | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.jpca.7b07449 | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1021/acs.jpca.7b07449 | - |
| dc.rights | info:eu-repo/semantics/restrictedAccess | - |
| dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | - |
| dc.source | reponame:CONICET Digital (CONICET) | - |
| dc.source | instname:Consejo Nacional de Investigaciones Científicas y Técnicas | - |
| dc.source | instacron:CONICET | - |
| dc.source.uri | http://hdl.handle.net/11336/64347 | - |
| dc.subject | FLUORINATED PEROXIDES | - |
| dc.subject | THERMAL REACTION | - |
| dc.subject | Otras Ciencias Químicas | - |
| dc.subject | Ciencias Químicas | - |
| dc.subject | CIENCIAS NATURALES Y EXACTAS | - |
| dc.title | Reaction of methyl fluoroformyl peroxycarbonate (FC(O)OOC(O)OCH3) with Cl atoms: Formation of hydro-chlorofluoro-peroxides | - |
| dc.type | info:eu-repo/semantics/article | - |
| dc.type | info:eu-repo/semantics/publishedVersion | - |
| dc.type | info:ar-repo/semantics/articulo | - |
| Aparece en las colecciones: | CONICET | |
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