Registro completo de metadatos
| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.creator | Ignaczak, Anna | - |
| dc.creator | Nazmutdinov, Renat | - |
| dc.creator | Goduljan, Aleksej | - |
| dc.creator | de Campos Pinto, Leandro Moreira | - |
| dc.creator | Juarez, Fernanda | - |
| dc.creator | Quaino, Paola Monica | - |
| dc.creator | Belletti, Gustavo Daniel | - |
| dc.creator | Santos, Elizabeth del Carmen | - |
| dc.creator | Schmickler, Wolfgang | - |
| dc.date | 2018-12-07T20:27:46Z | - |
| dc.date | 2018-12-07T20:27:46Z | - |
| dc.date | 2017-11 | - |
| dc.date | 2018-11-27T16:35:00Z | - |
| dc.date.accessioned | 2019-04-29T15:45:56Z | - |
| dc.date.available | 2019-04-29T15:45:56Z | - |
| dc.date.issued | 2017-11 | - |
| dc.identifier | Ignaczak, Anna; Nazmutdinov, Renat; Goduljan, Aleksej; de Campos Pinto, Leandro Moreira; Juarez, Fernanda; et al.; Oxygen Reduction in Alkaline Media—a Discussion; Springer New York LLC; Electrocatalysis; 8; 6; 11-2017; 554-564 | - |
| dc.identifier | 1868-5994 | - |
| dc.identifier | http://hdl.handle.net/11336/66108 | - |
| dc.identifier | CONICET Digital | - |
| dc.identifier | CONICET | - |
| dc.identifier.uri | http://rodna.bn.gov.ar:8080/jspui/handle/bnmm/301454 | - |
| dc.description | We propose a complete reaction sequence for oxygen reduction in alkaline solutions, in which the first two steps occur in the outer sphere mode. The oxygen-oxygen bond is broken in the third step, which involves adsorption of OH, which is desorbed in the last step. We have investigated the sequence by quantum-chemical methods and determined the energies of activation. Whether the reaction follows a four- or a two-electron mechanism, depends critically on the energy of adsorption of OH. We surmise that our mechanism holds on all electrodes which interact weakly with oxygen, in particular on gold, silver, and graphite. We explain, why Au(100) is a better catalyst than Au(111), why at high overpotentials the reaction on Au(100) reverts to a two-electron mechanism, and why this does not happen on silver. [Figure not available: see fulltext.] | - |
| dc.description | Fil: Ignaczak, Anna. University Of Lodz; Argentina | - |
| dc.description | Fil: Nazmutdinov, Renat. Kazan National Research Technological University; Rusia | - |
| dc.description | Fil: Goduljan, Aleksej. Universitat Ulm; Alemania | - |
| dc.description | Fil: de Campos Pinto, Leandro Moreira. Universitat Ulm; Alemania. Instituto de Química Universidade Federal de Mato Grosso do Sul; Brasil | - |
| dc.description | Fil: Juarez, Fernanda. Universitat Ulm; Alemania | - |
| dc.description | Fil: Quaino, Paola Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina | - |
| dc.description | Fil: Belletti, Gustavo Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Electroquímica Aplicada e Ingeniería Electroquímica; Argentina | - |
| dc.description | Fil: Santos, Elizabeth del Carmen. Universitat Ulm; Alemania. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; Argentina | - |
| dc.description | Fil: Schmickler, Wolfgang. Universitat Ulm; Alemania | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.language | eng | - |
| dc.publisher | Springer New York LLC | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/url/http://link.springer.com/article/10.1007/s12678-017-0365-y | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/https://doi.org/10.1007/s12678-017-0365-y | - |
| dc.rights | info:eu-repo/semantics/restrictedAccess | - |
| dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | - |
| dc.source | reponame:CONICET Digital (CONICET) | - |
| dc.source | instname:Consejo Nacional de Investigaciones Científicas y Técnicas | - |
| dc.source | instacron:CONICET | - |
| dc.subject | ALKALINE FUEL CELLS | - |
| dc.subject | DFT | - |
| dc.subject | ELECTRON TRANSFER | - |
| dc.subject | OXYGEN REDUCTION | - |
| dc.subject | Astronomía | - |
| dc.subject | Ciencias Físicas | - |
| dc.subject | CIENCIAS NATURALES Y EXACTAS | - |
| dc.subject | Otras Ciencias Químicas | - |
| dc.subject | Ciencias Químicas | - |
| dc.subject | CIENCIAS NATURALES Y EXACTAS | - |
| dc.title | Oxygen Reduction in Alkaline Media—a Discussion | - |
| dc.type | info:eu-repo/semantics/article | - |
| dc.type | info:eu-repo/semantics/publishedVersion | - |
| dc.type | info:ar-repo/semantics/articulo | - |
| Aparece en las colecciones: | CONICET | |
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