Registro completo de metadatos
| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.provenance | CONICET | - |
| dc.creator | Rougier, Natalia Mercedes | - |
| dc.creator | Vico, Raquel Viviana | - |
| dc.creator | Hoyos, Maria Rita Micaela | - |
| dc.creator | Bujan, Elba Ines | - |
| dc.date | 2017-12-26T18:34:09Z | - |
| dc.date | 2017-12-26T18:34:09Z | - |
| dc.date | 2014-11 | - |
| dc.date | 2017-12-21T16:28:03Z | - |
| dc.date.accessioned | 2019-04-29T15:47:15Z | - |
| dc.date.available | 2019-04-29T15:47:15Z | - |
| dc.date.issued | 2017-12-26T18:34:09Z | - |
| dc.date.issued | 2017-12-26T18:34:09Z | - |
| dc.date.issued | 2014-11 | - |
| dc.date.issued | 2017-12-21T16:28:03Z | - |
| dc.identifier | Bujan, Elba Ines; Hoyos, Maria Rita Micaela; Vico, Raquel Viviana; Rougier, Natalia Mercedes; Stabilization of the pesticide Fenitrothion toward O and N nucleophiles in the presence of cyclodextrins; John Wiley & Sons Ltd; Journal Of Physical Organic Chemistry; 27; 12; 11-2014; 935-943 | - |
| dc.identifier | 0894-3230 | - |
| dc.identifier | http://hdl.handle.net/11336/31558 | - |
| dc.identifier | CONICET Digital | - |
| dc.identifier | CONICET | - |
| dc.identifier.uri | http://rodna.bn.gov.ar:8080/jspui/handle/bnmm/301986 | - |
| dc.description | The reaction of Fenitrothion with O and N nucleophiles (H2O2, NH2OH, n-butylamine and piperidine) was studied at 25 °C in water containing 2% 1,4-dioxane in the presence of native cyclodextrins (α-, β-, and γ-CD). For all the nucleophiles, the presence of CD produces reaction inhibition with saturation kinetics. The greatest effect in all cases is observed with β-CD, and the greatest inhibition was observed for the reaction of Fenitrothion with H2O2 (81%), which is the most efficient nucleophile in promoting Fenitrothion degradation in homogeneous media. In the absence of CD, competition between the SN2(P) and the SN2(C) pathways was observed with piperidine as was reported before for the reaction with NH2OH and n-butylamine. The presence of β-CD does not modify product distribution in the case of the reaction with NH2OH and n-butylamine, whereas there is an increase in SN2(C) pathway when the nucleophile is piperidine. | - |
| dc.description | Fil: Rougier, Natalia Mercedes. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina | - |
| dc.description | Fil: Vico, Raquel Viviana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina | - |
| dc.description | Fil: Hoyos, Maria Rita Micaela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina | - |
| dc.description | Fil: Bujan, Elba Ines. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.language | eng | - |
| dc.publisher | John Wiley & Sons Ltd | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1002/poc.3373 | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/poc.3373/abstract | - |
| dc.rights | info:eu-repo/semantics/restrictedAccess | - |
| dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | - |
| dc.source | reponame:CONICET Digital (CONICET) | - |
| dc.source | instname:Consejo Nacional de Investigaciones Científicas y Técnicas | - |
| dc.source | instacron:CONICET | - |
| dc.source.uri | http://hdl.handle.net/11336/31558 | - |
| dc.subject | AMINOLYSIS | - |
| dc.subject | CYCLODEXTRINS | - |
| dc.subject | HOST GUEST SYSTEMS | - |
| dc.subject | HYDROGEN PEROXIDE | - |
| dc.subject | INCLUSION COMPLEXES | - |
| dc.subject | ORGANOPHOSPHORUS INSECTICIDES | - |
| dc.subject | REACTION MECHANISMS | - |
| dc.subject | Otras Ciencias Químicas | - |
| dc.subject | Ciencias Químicas | - |
| dc.subject | CIENCIAS NATURALES Y EXACTAS | - |
| dc.title | Stabilization of the pesticide Fenitrothion toward O and N nucleophiles in the presence of cyclodextrins | - |
| dc.type | info:eu-repo/semantics/article | - |
| dc.type | info:eu-repo/semantics/publishedVersion | - |
| dc.type | info:ar-repo/semantics/articulo | - |
| Aparece en las colecciones: | CONICET | |
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