Registro completo de metadatos
| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.provenance | CONICET | - |
| dc.creator | Soria Castro, Silvia Mercedes | - |
| dc.date | 2018-10-26T21:46:52Z | - |
| dc.date | 2018-10-26T21:46:52Z | - |
| dc.date | 2012-11-16 | - |
| dc.date | 2018-09-18T16:15:22Z | - |
| dc.date.accessioned | 2019-04-29T15:47:59Z | - |
| dc.date.available | 2019-04-29T15:47:59Z | - |
| dc.date.issued | 2012-11-16 | - |
| dc.identifier | Soria Castro, Silvia Mercedes; Potassium thioacetate; Georg Thieme Verlag Kg; Synlett; 23; 20; 16-11-2012; 2997-2998 | - |
| dc.identifier | 0936-5214 | - |
| dc.identifier | http://hdl.handle.net/11336/63154 | - |
| dc.identifier | 0936-5214 | - |
| dc.identifier | CONICET Digital | - |
| dc.identifier | CONICET | - |
| dc.identifier.uri | http://rodna.bn.gov.ar:8080/jspui/handle/bnmm/302339 | - |
| dc.description | Potassium thioacetate (AcSK) is an off-white to lightbrown crystalline powder that is air sensitive, hygroscopic, and commercially available. It is soluble in water and stable under standard temperature and pressure (m.p. 173–176 °C). This reagent is widely used as a sulfur source in the synthesis of sulfur-containing organic compounds. The formation of C–S bonds can be easily accomplished by reacting potassium thioacetate with aryl, benzyl, alkyl and vinyl halides or arenediazonium salts, to obtain the corresponding thioesters. A later deprotection allows straightforward access to the thiol since acyl groups may be removed under mild conditions. Thus, potassium thioacetate is a versatile reagent that can participate in numerous reactions such as nucleophilic substitutions, transition-metal-catalyzed couplings, photoinduced substitutions, vinylic substitutions and reductive amidation of nitro arenes. Therefore, this reagent has been employed for the synthesis of heterocycles,1 polymers,2 transition-metal ligands,3 nanoparticles,4 bioactive compounds5 and macromolecular inclusion complexes | - |
| dc.description | Fil: Soria Castro, Silvia Mercedes. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.language | eng | - |
| dc.publisher | Georg Thieme Verlag Kg | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/url/https://www.thieme-connect.de/DOI/DOI?10.1055/s-0031-1290470 | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1055/s-0031-1290470 | - |
| dc.rights | info:eu-repo/semantics/restrictedAccess | - |
| dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | - |
| dc.source | reponame:CONICET Digital (CONICET) | - |
| dc.source | instname:Consejo Nacional de Investigaciones Científicas y Técnicas | - |
| dc.source | instacron:CONICET | - |
| dc.source.uri | http://hdl.handle.net/11336/63154 | - |
| dc.subject | POTASSIUM THIOACETATE | - |
| dc.subject | CRYSTALLINE POWDER | - |
| dc.subject | REACTIONS | - |
| dc.subject | Otras Ciencias Químicas | - |
| dc.subject | Ciencias Químicas | - |
| dc.subject | CIENCIAS NATURALES Y EXACTAS | - |
| dc.title | Potassium thioacetate | - |
| dc.type | info:eu-repo/semantics/article | - |
| dc.type | info:eu-repo/semantics/publishedVersion | - |
| dc.type | info:ar-repo/semantics/articulo | - |
| Aparece en las colecciones: | CONICET | |
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