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dc.provenanceCONICET-
dc.creatorBorrero Gonzalez, Luis Jose-
dc.creatorNunes, L. A. O.-
dc.creatorGuimaraes, F. E. G.-
dc.creatorWojcik, J.-
dc.creatorMascher, P.-
dc.creatorGennaro, Ana Maria-
dc.creatorTirado, Monica Cecilia-
dc.creatorComedi, David Mario-
dc.date2017-06-23T20:23:22Z-
dc.date2017-06-23T20:23:22Z-
dc.date2012-06-
dc.date2017-06-21T18:38:27Z-
dc.date.accessioned2019-04-29T15:47:59Z-
dc.date.available2019-04-29T15:47:59Z-
dc.date.issued2012-06-
dc.identifierBorrero Gonzalez, Luis Jose; Nunes, L. A. O.; Guimaraes, F. E. G.; Wojcik, J.; Mascher, P.; et al.; Growing Si Nanocrystals within a-Si Nanoclusters Embedded in a-SiO2: Evolution of Photoluminescence; The Electrochemical Society; ECS Transactions; 45; 5; 6-2012; 11-19-
dc.identifier1938-6737-
dc.identifierhttp://hdl.handle.net/11336/18807-
dc.identifierCONICET Digital-
dc.identifierCONICET-
dc.identifier.urihttp://rodna.bn.gov.ar:8080/jspui/handle/bnmm/302342-
dc.descriptionWe combine X-ray absorption, electron spin resonance and Raman spectroscopies, X-ray diffraction and photoluminescence (PL) techniques to determine the structure and luminescence mechanisms in Si nanoclusters (Si-ncls) embedded within Si oxides at various intermediate formation stages. The Si-ncls/oxide systems are fabricated by thermally annealing plasma-enhanced chemical vapor deposited Si-rich Si-oxide films. The structural and chemical orders in the amorphous oxide matrix, the Si-ncls amorphous and crystalline volume fractions and sizes, the dangling bond density and PL spectra and decay rates are followed closely as a function of the annealing temperature. The results can be interpreted by a crystalline core/amorphous shell model for the Sincls. The important role of the shell, often ignored in the literature, is discussed. As the Si-ncls crystalline cores grow at the expense of thinning amorphous shells, the PL undergoes a transition from a regime dominated by disorder-induced effects to a situation where quantum confinement prevails.-
dc.descriptionFil: Borrero Gonzalez, Luis Jose. Universidade de São Paulo; Brasil-
dc.descriptionFil: Nunes, L. A. O.. Universidade de São Paulo; Brasil-
dc.descriptionFil: Guimaraes, F. E. G.. Universidade de São Paulo; Brasil-
dc.descriptionFil: Wojcik, J.. McMaster University; Canadá-
dc.descriptionFil: Mascher, P.. McMaster University; Canadá-
dc.descriptionFil: Gennaro, Ana Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina-
dc.descriptionFil: Tirado, Monica Cecilia. Universidad Nacional de Tucumán; Argentina-
dc.descriptionFil: Comedi, David Mario. Universidad Nacional de Tucumán; Argentina-
dc.formatapplication/pdf-
dc.formatapplication/pdf-
dc.languageeng-
dc.publisherThe Electrochemical Society-
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1149/1.3700405-
dc.relationinfo:eu-repo/semantics/altIdentifier/url/http://ecst.ecsdl.org/content/45/5/11-
dc.rightsinfo:eu-repo/semantics/restrictedAccess-
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/-
dc.sourcereponame:CONICET Digital (CONICET)-
dc.sourceinstname:Consejo Nacional de Investigaciones Científicas y Técnicas-
dc.sourceinstacron:CONICET-
dc.source.urihttp://hdl.handle.net/11336/18807-
dc.subjectSi-rich Si Oxides-
dc.subjectX-ray diffraction-
dc.subjectElectron spin resonance spectroscopy-
dc.subjectRaman spectroscopy-
dc.subjectFísica de los Materiales Condensados-
dc.subjectCiencias Físicas-
dc.subjectCIENCIAS NATURALES Y EXACTAS-
dc.titleGrowing Si Nanocrystals within a-Si Nanoclusters Embedded in a-SiO2: Evolution of Photoluminescence-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/publishedVersion-
dc.typeinfo:ar-repo/semantics/articulo-
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