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Campo DC | Valor | Lengua/Idioma |
---|---|---|
dc.creator | Quiroga, Monica Esther | - |
dc.creator | Liprandi, Domingo Antonio | - |
dc.creator | Cagnola, Edgardo Alberto | - |
dc.creator | L' Argentière, P.C. | - |
dc.date | 2018-11-27T16:59:18Z | - |
dc.date | 2018-11-27T16:59:18Z | - |
dc.date | 2007-07 | - |
dc.date | 2018-11-22T14:26:46Z | - |
dc.date.accessioned | 2019-04-29T15:48:57Z | - |
dc.date.available | 2019-04-29T15:48:57Z | - |
dc.date.issued | 2007-07 | - |
dc.identifier | Quiroga, Monica Esther; Liprandi, Domingo Antonio; Cagnola, Edgardo Alberto; L' Argentière, P.C.; 1-Heptyne semihydrogenation catalized by palladium or rhodium complexes. Influence of: metal atom, ligands and the homo/heterogeneous condition; Elsevier Science; Applied Catalysis A: General; 326; 2; 7-2007; 121-129 | - |
dc.identifier | 0926-860X | - |
dc.identifier | http://hdl.handle.net/11336/65324 | - |
dc.identifier | CONICET Digital | - |
dc.identifier | CONICET | - |
dc.identifier.uri | http://rodna.bn.gov.ar:8080/jspui/handle/bnmm/302792 | - |
dc.description | [RhCl(TDA)3], [RhCl(HA)3], [PdCl2(TDA)2] and [PdCl2(HA)2] (TDA = tridecylamine, HA = hexylamine) were synthesized and tested as catalysts in homogeneous and heterogeneous condition for the 1-heptyne semihydrogenation, using γ-alumina as support. The Lindlar catalyst was used as a reference. XPS, FTIR and Atomic Absorption results showed that the active catalytic species in each case is the complex itself. All of the catalytic systems exhibited a better performance than the Lindlar catalyst, with the exception of [PdCl2(HA)2]. The analysis of activity and selectivity values allowed to say that the best system is [RhCl(TDA)3]/Al2O3, an heterogeneous catalyst with an electron-rich transition metal and an electron-donating ligand (TDA) containing a long-chain hydrocarbon substituent. The complex system catalytic behaviour could be explained by means of electronic and geometric effects. | - |
dc.description | Fil: Quiroga, Monica Esther. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina | - |
dc.description | Fil: Liprandi, Domingo Antonio. Universidad Nacional del Litoral; Argentina | - |
dc.description | Fil: Cagnola, Edgardo Alberto. Universidad Nacional del Litoral; Argentina | - |
dc.description | Fil: L' Argentière, P.C.. Universidad Nacional del Litoral; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina | - |
dc.format | application/pdf | - |
dc.format | application/pdf | - |
dc.format | application/pdf | - |
dc.format | application/pdf | - |
dc.format | application/pdf | - |
dc.language | eng | - |
dc.publisher | Elsevier Science | - |
dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.apcata.2007.03.035 | - |
dc.rights | info:eu-repo/semantics/restrictedAccess | - |
dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | - |
dc.source | reponame:CONICET Digital (CONICET) | - |
dc.source | instname:Consejo Nacional de Investigaciones Científicas y Técnicas | - |
dc.source | instacron:CONICET | - |
dc.subject | 1-HEPTYNE SEMIHYDROGENATION | - |
dc.subject | Rh/Pd COMPLEXES | - |
dc.subject | COORDINATION SPHERE | - |
dc.subject | HOMO/HETEROGENEUS CONDITION | - |
dc.subject | Otras Ingeniería Química | - |
dc.subject | Ingeniería Química | - |
dc.subject | INGENIERÍAS Y TECNOLOGÍAS | - |
dc.title | 1-Heptyne semihydrogenation catalized by palladium or rhodium complexes. Influence of: metal atom, ligands and the homo/heterogeneous condition | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/publishedVersion | - |
dc.type | info:ar-repo/semantics/articulo | - |
Aparece en las colecciones: | CONICET |
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