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dc.creatorGerbino, Darío César-
dc.creatorMandolesi, Sandra Delia-
dc.creatorSchmalz, Hans Günther-
dc.creatorPodestá, Julio Cesar-
dc.date2018-12-04T14:58:45Z-
dc.date2018-12-04T14:58:45Z-
dc.date2009-08-
dc.date2018-11-22T14:31:07Z-
dc.date.accessioned2019-04-29T15:49:44Z-
dc.date.available2019-04-29T15:49:44Z-
dc.date.issued2009-08-
dc.identifierGerbino, Darío César; Mandolesi, Sandra Delia; Schmalz, Hans Günther; Podestá, Julio Cesar; Introduction of allyi and prenyl side-chains into aromatic systems by suzuki cross-coupling reactions; Wiley VCH Verlag; European Journal of Organic Chemistry; 23; 8-2009; 3964-3972-
dc.identifier1434-193X-
dc.identifierhttp://hdl.handle.net/11336/65714-
dc.identifierCONICET Digital-
dc.identifierCONICET-
dc.identifier.urihttp://rodna.bn.gov.ar:8080/jspui/handle/bnmm/303127-
dc.descriptionThis paper reports some studies aiming at the developement of a general protocol useful for the synthesis of allyl- and prenylaromatic compounds. The first part deals with, the preparation of boron reagents like arylboronic acids and their pinacol esters as well as of pinacol allyl- and prenylboronates. The second part of the paper is devoted to the use of these boron reagents in Suzuki-Miyaura cross-coupling reactions leading to allylation and prenylation of aromatic compounds. Of the six methods studied, the most promising re-suits were obtained by using the Pd2(dba)3-catalyzed reactions of arylboronic acids with allyl and prenyl bromides, that lead to the products of cross coupling in high yields (average 87%), and the reactions of aryl trifluoroborates with allyl and prenyl bromides catalyzed by Pd(OAc)2 that lead to the products of coupling in all cases in high yields (average 82%). © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.-
dc.descriptionFil: Gerbino, Darío César. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina-
dc.descriptionFil: Mandolesi, Sandra Delia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina-
dc.descriptionFil: Schmalz, Hans Günther. Universität zu Köln; Alemania-
dc.descriptionFil: Podestá, Julio Cesar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina-
dc.formatapplication/pdf-
dc.formatapplication/pdf-
dc.formatapplication/pdf-
dc.formatapplication/pdf-
dc.languageeng-
dc.publisherWiley VCH Verlag-
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/https://dx.doi.org/10.1002/ejoc.200900234-
dc.relationinfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/ejoc.200900234-
dc.rightsinfo:eu-repo/semantics/restrictedAccess-
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/-
dc.sourcereponame:CONICET Digital (CONICET)-
dc.sourceinstname:Consejo Nacional de Investigaciones Científicas y Técnicas-
dc.sourceinstacron:CONICET-
dc.subjectARENES-
dc.subjectBORATES-
dc.subjectBORON-
dc.subjectCROSS-COUPLING-
dc.subjectOtras Ciencias Químicas-
dc.subjectCiencias Químicas-
dc.subjectCIENCIAS NATURALES Y EXACTAS-
dc.titleIntroduction of allyi and prenyl side-chains into aromatic systems by suzuki cross-coupling reactions-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/publishedVersion-
dc.typeinfo:ar-repo/semantics/articulo-
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