Registro completo de metadatos
Campo DC | Valor | Lengua/Idioma |
---|---|---|
dc.creator | Vega, Jorge Ruben | - |
dc.creator | Gugliotta, Luis Marcelino | - |
dc.creator | Meira, Gregorio Raul | - |
dc.date | 2017-11-20T21:08:11Z | - |
dc.date | 2017-11-20T21:08:11Z | - |
dc.date | 2003-05 | - |
dc.date | 2017-11-16T14:46:04Z | - |
dc.date.accessioned | 2019-04-29T15:51:26Z | - |
dc.date.available | 2019-04-29T15:51:26Z | - |
dc.date.issued | 2003-05 | - |
dc.identifier | Vega, Jorge Ruben; Gugliotta, Luis Marcelino; Meira, Gregorio Raul; Emulsion Copolymerization of Acrylonitrile and Butadiene in an Industrial Reactor. Mathematical Modelling, Estimation, and Control of Polymer Quality Variables on the Basis of Calorimetric Measurements; Plapiqui; Latin American Applied Research; 33; 2; 5-2003; 115-122 | - |
dc.identifier | 0327-0793 | - |
dc.identifier | http://hdl.handle.net/11336/28555 | - |
dc.identifier | 1851-8796 | - |
dc.identifier | CONICET Digital | - |
dc.identifier | CONICET | - |
dc.identifier.uri | http://rodna.bn.gov.ar:8080/jspui/handle/bnmm/303854 | - |
dc.description | An industrial emulsion copolymerization of acrylonitrile and butadiene carried out in a batch (or semibatch) reactor for the production of nitrile rubber (NBR) is investigated. The effect of variable amounts of deactivating impurities on the predictions of a global polymerization model is analyzed; and the advantages of using the model predictions in combination with on-line calorimetric measurements are shown. The adjusted polymerization model allows to adequately monitor main quality variables of the process, such as: monomer conversion, average copolymer composition, average molecular weights, and degree of branching. The semibatch addition of the comonomers and/or the chain transfer agent along the reaction was investigated with the aim of controlling the polymer quality characteristics and increasing the productivity. It is possible to obtain a uniform-composition copolymer with pre-specified profiles of the average molecular weights or the degrees of branching. Furthermore, the NBR productivity can be increased by about 5%, without deteriorating the final copolymer quality with respect to that produced in the more conventional batch operation. | - |
dc.description | Fil: Vega, Jorge Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina | - |
dc.description | Fil: Gugliotta, Luis Marcelino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina | - |
dc.description | Fil: Meira, Gregorio Raul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina | - |
dc.format | application/pdf | - |
dc.format | application/pdf | - |
dc.format | application/pdf | - |
dc.language | eng | - |
dc.publisher | Plapiqui | - |
dc.relation | info:eu-repo/semantics/altIdentifier/url/http://www.laar.uns.edu.ar/indexes/artic_v3302/pag115.pdf | - |
dc.rights | info:eu-repo/semantics/openAccess | - |
dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | - |
dc.source | reponame:CONICET Digital (CONICET) | - |
dc.source | instname:Consejo Nacional de Investigaciones Científicas y Técnicas | - |
dc.source | instacron:CONICET | - |
dc.subject | Otras Ingeniería Química | - |
dc.subject | Ingeniería Química | - |
dc.subject | INGENIERÍAS Y TECNOLOGÍAS | - |
dc.title | Emulsion Copolymerization of Acrylonitrile and Butadiene in an Industrial Reactor. Mathematical Modelling, Estimation, and Control of Polymer Quality Variables on the Basis of Calorimetric Measurements | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/publishedVersion | - |
dc.type | info:ar-repo/semantics/articulo | - |
Aparece en las colecciones: | CONICET |
Ficheros en este ítem:
No hay ficheros asociados a este ítem.