Registro completo de metadatos
| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.creator | Gomez, Germán Ernesto | - |
| dc.creator | Bernini, Maria Celeste | - |
| dc.creator | Brusau, Elena Virginia | - |
| dc.creator | Narda, Griselda Edith | - |
| dc.creator | Massad, Walter Alfredo | - |
| dc.creator | Labrador, Ana | - |
| dc.date | 2015-10-01T19:12:38Z | - |
| dc.date | 2015-10-01T19:12:38Z | - |
| dc.date | 2013-10 | - |
| dc.date | 2016-03-30 10:35:44.97925-03 | - |
| dc.date.accessioned | 2019-04-29T15:51:27Z | - |
| dc.date.available | 2019-04-29T15:51:27Z | - |
| dc.date.issued | 2013-10 | - |
| dc.identifier | Gomez, Germán Ernesto; Bernini, Maria Celeste; Brusau, Elena Virginia; Narda, Griselda Edith; Massad, Walter Alfredo; et al.; Two Sets of Metal Organic Frameworks along the Lanthanide Series Constructed by 2,3-Dimethylsuccinate: Structures, Topologies, and Strong Emission without Ligand Sensitization; American Chemical Society; Crystal Growth & Design; 13; 12; 10-2013; 5249-5260 | - |
| dc.identifier | 1528-7483 | - |
| dc.identifier | http://hdl.handle.net/11336/2276 | - |
| dc.identifier.uri | http://rodna.bn.gov.ar:8080/jspui/handle/bnmm/303860 | - |
| dc.description | Reactions in aqueous solution under hydrothermal conditions between (±)-2,3-dimethylsuccinic acid and lanthanide chlorides lead to two different isostructural types with chemical formulas [Ln2(C6H8O4)3(H2O)2] Ln(III) = Pr−Eu (except Pm) (Type I, compounds 1−4) and [Ln2(C6H8O4)3] Ln(III) = Tb−Yb (except Tm) (Type II, compounds 5−9). The crystal structure has been solved for the Pr (1)-, Sm (3)-, and Ho (7)-containing compounds by means of single-crystal XRD methods, whereas powder XRD Rietveld refinement was used for the rest of the MOFs. Compounds 1−4 crystallize in the triclinic space group P1̅, whereas compounds 5−9 belong to the tetragonal space group P43212. Type I and II compounds are 3D frameworks consisting of chains of [LnO8(H2O)] or [LnO8] polyhedra, respectively, linked by dimethylsuccinate anions, giving rise to I1 O2 connectivity. All the compounds were characterized by X-ray diffraction, variable-temperature Fourier transform infrared spectroscopy, and thermal analysis. An exhaustive topological study was performed in comparison with other related compounds. The photoluminescent (PL) properties for compounds 3, 4, and 5 have been also explored, indicating that a metal-centered luminescent process takes place. | - |
| dc.description | Fil: Gomez, Germán Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Investigaciones en Tecnología Química; Argentina; Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Area Química General e Inorgánica; Argentina; | - |
| dc.description | Fil: Bernini, Maria Celeste. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina; Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Area Química General e Inorgánica; Argentina; Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Investigaciones en Tecnología Química; Argentina; | - |
| dc.description | Fil: Brusau, Elena Virginia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Investigaciones en Tecnología Química; Argentina; Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Area Química General e Inorgánica; Argentina; | - |
| dc.description | Fil: Narda, Griselda Edith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Investigaciones en Tecnología Química; Argentina; Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Area Química General e Inorgánica; Argentina; | - |
| dc.description | Fil: Massad, Walter Alfredo. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina; | - |
| dc.description | Fil: Labrador, Ana. Lund University. MAX IV Laboratory; Suecia; | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.language | eng | - |
| dc.publisher | American Chemical Society | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1021/cg401006d | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/cg401006d | - |
| dc.rights | info:eu-repo/semantics/restrictedAccess | - |
| dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | - |
| dc.source | reponame:CONICET Digital (CONICET) | - |
| dc.source | instname:Consejo Nacional de Investigaciones Científicas y Técnicas | - |
| dc.source | instacron:CONICET | - |
| dc.subject | LANTHANIDE | - |
| dc.subject | MOFs | - |
| dc.subject | LUMINISCENCE | - |
| dc.subject | TOPOLOGY | - |
| dc.subject | Química Inorgánica y Nuclear | - |
| dc.subject | Ciencias Químicas | - |
| dc.subject | CIENCIAS NATURALES Y EXACTAS | - |
| dc.title | Two Sets of Metal Organic Frameworks along the Lanthanide Series Constructed by 2,3-Dimethylsuccinate: Structures, Topologies, and Strong Emission without Ligand Sensitization | - |
| dc.type | info:eu-repo/semantics/article | - |
| dc.type | info:eu-repo/semantics/publishedVersion | - |
| dc.type | info:ar-repo/semantics/articulo | - |
| Aparece en las colecciones: | CONICET | |
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