Registro completo de metadatos
| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.creator | Baquero, Edwin A. | - |
| dc.creator | Silbestri, Gustavo Fabián | - |
| dc.creator | Flores, Juan C. | - |
| dc.creator | De Jesús, Ernesto | - |
| dc.date | 2018-08-16T15:20:27Z | - |
| dc.date | 2018-08-16T15:20:27Z | - |
| dc.date | 2017-06 | - |
| dc.date | 2018-08-10T16:23:05Z | - |
| dc.date.accessioned | 2019-04-29T15:51:30Z | - |
| dc.date.available | 2019-04-29T15:51:30Z | - |
| dc.date.issued | 2017-06 | - |
| dc.identifier | Baquero, Edwin A.; Silbestri, Gustavo Fabián; Flores, Juan C.; De Jesús, Ernesto; Solvent-Reversible Addition of Alkyne C-H Bonds to Water-Soluble NHC Platinum(0) Complexes; American Chemical Society; Organometallics; 36; 12; 6-2017; 2271-2274 | - |
| dc.identifier | 0276-7333 | - |
| dc.identifier | http://hdl.handle.net/11336/55885 | - |
| dc.identifier | CONICET Digital | - |
| dc.identifier | CONICET | - |
| dc.identifier.uri | http://rodna.bn.gov.ar:8080/jspui/handle/bnmm/303887 | - |
| dc.description | Oxidative addition of CH3I and alkynes to the platinum(0) complex [Pt(AE)NHC] (1), in which the NHC ligand is a sulfonated version of the IPr ligand (1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) and AE is diallyl ether, is reported. Reaction with the haloalkane affords the iodomethyl complex [PtI(Me)NHC] (2), whereas the addition of alkynes via C(sp)-H bond activation leads to the corresponding new water-soluble hydride (NHC)PtII complexes 3 and 4. Complexes 3 and 4 were found to be moderately stable in water, displaying an interesting behavior in this solvent. Thus, in the presence of the corresponding olefin, the reaction can be reversible under mild conditions, thus allowing the formation of diolefinic (NHC)Pt0 complexes 1, 5, and 6, with elimination of the alkyne. | - |
| dc.description | Fil: Baquero, Edwin A.. Universidad de Alcalá; España. Universidad Nacional de Colombia; Colombia | - |
| dc.description | Fil: Silbestri, Gustavo Fabián. Universidad de Alcalá; España. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina | - |
| dc.description | Fil: Flores, Juan C.. Universidad de Alcalá; España | - |
| dc.description | Fil: De Jesús, Ernesto. Universidad de Alcalá; España | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.language | eng | - |
| dc.publisher | American Chemical Society | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1021/acs.organomet.7b00207 | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.organomet.7b00207 | - |
| dc.rights | info:eu-repo/semantics/restrictedAccess | - |
| dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | - |
| dc.source | reponame:CONICET Digital (CONICET) | - |
| dc.source | instname:Consejo Nacional de Investigaciones Científicas y Técnicas | - |
| dc.source | instacron:CONICET | - |
| dc.subject | NHC-PlLATINUM | - |
| dc.subject | WATER SOLUBLE NHC | - |
| dc.subject | ALKYNE | - |
| dc.subject | Otras Ciencias Químicas | - |
| dc.subject | Ciencias Químicas | - |
| dc.subject | CIENCIAS NATURALES Y EXACTAS | - |
| dc.title | Solvent-Reversible Addition of Alkyne C-H Bonds to Water-Soluble NHC Platinum(0) Complexes | - |
| dc.type | info:eu-repo/semantics/article | - |
| dc.type | info:eu-repo/semantics/publishedVersion | - |
| dc.type | info:ar-repo/semantics/articulo | - |
| Aparece en las colecciones: | CONICET | |
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