Registro completo de metadatos
| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.creator | Gandolfi Donadío, Lucía | - |
| dc.creator | Galetti, Mariana Alejandra | - |
| dc.creator | Giorgi, Gianluca | - |
| dc.creator | Rasparini, Marcello | - |
| dc.creator | Comin, Maria Julieta | - |
| dc.date | 2018-08-01T13:38:50Z | - |
| dc.date | 2018-08-01T13:38:50Z | - |
| dc.date | 2016-09 | - |
| dc.date | 2018-07-25T13:57:18Z | - |
| dc.date.accessioned | 2019-04-29T15:52:51Z | - |
| dc.date.available | 2019-04-29T15:52:51Z | - |
| dc.date.issued | 2016-09 | - |
| dc.identifier | Gandolfi Donadío, Lucía; Galetti, Mariana Alejandra; Giorgi, Gianluca; Rasparini, Marcello; Comin, Maria Julieta; Anti-Selective Organocatalytic Michael Addition between Phenylacetaldehyde and Nitrostyrene; American Chemical Society; Journal of Organic Chemistry; 81; 17; 9-2016; 7952-7957 | - |
| dc.identifier | 0022-3263 | - |
| dc.identifier | http://hdl.handle.net/11336/53729 | - |
| dc.identifier | CONICET Digital | - |
| dc.identifier | CONICET | - |
| dc.identifier.uri | http://rodna.bn.gov.ar:8080/jspui/handle/bnmm/304480 | - |
| dc.description | Using the reaction between phenylacetaldehyde and nitrostyrene catalyzed by pyrrolidine as a simple model, we have studied the diastereochemical outcome of the organocatalytic Michael reactions between benzylic aldehydes and nitrostyrenes. We found that the anti adduct was obtained in high yield and diastereoselection as was demonstrated by the X-ray structure of the product. In situ NMR studies showed a different reaction pathway when compared to aliphatic aldehydes that yield the syn adduct as major isomer. | - |
| dc.description | Fil: Gandolfi Donadío, Lucía. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Instituto Nacional de Tecnología Industrial. Centro de Investigación y Desarrollo en Química; Argentina | - |
| dc.description | Fil: Galetti, Mariana Alejandra. Instituto Nacional de Tecnología Industrial. Centro de Investigación y Desarrollo en Química; Argentina | - |
| dc.description | Fil: Giorgi, Gianluca. Università degli Studi di Siena; Italia | - |
| dc.description | Fil: Rasparini, Marcello. Chemessentia SRL; Italia | - |
| dc.description | Fil: Comin, Maria Julieta. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Instituto Nacional de Tecnología Industrial. Centro de Investigación y Desarrollo en Química; Argentina | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.language | eng | - |
| dc.publisher | American Chemical Society | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/https://dx.doi.org/10.1021/acs.joc.6b01061 | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.joc.6b01061 | - |
| dc.rights | info:eu-repo/semantics/restrictedAccess | - |
| dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | - |
| dc.source | reponame:CONICET Digital (CONICET) | - |
| dc.source | instname:Consejo Nacional de Investigaciones Científicas y Técnicas | - |
| dc.source | instacron:CONICET | - |
| dc.subject | Michael addition | - |
| dc.subject | phenylacetheldehyde | - |
| dc.subject | Organocatalyst | - |
| dc.subject | Otras Ciencias Químicas | - |
| dc.subject | Ciencias Químicas | - |
| dc.subject | CIENCIAS NATURALES Y EXACTAS | - |
| dc.title | Anti-Selective Organocatalytic Michael Addition between Phenylacetaldehyde and Nitrostyrene | - |
| dc.type | info:eu-repo/semantics/article | - |
| dc.type | info:eu-repo/semantics/publishedVersion | - |
| dc.type | info:ar-repo/semantics/articulo | - |
| Aparece en las colecciones: | CONICET | |
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