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dc.provenanceCONICET-
dc.creatorBertero, Melisa Paola-
dc.creatorSedran, Ulises Anselmo-
dc.date2017-07-24T20:14:47Z-
dc.date2017-07-24T20:14:47Z-
dc.date2013-09-
dc.date2017-07-24T18:52:40Z-
dc.date.accessioned2019-04-29T15:53:22Z-
dc.date.available2019-04-29T15:53:22Z-
dc.date.issued2013-09-
dc.identifierBertero, Melisa Paola; Sedran, Ulises Anselmo; Upgrading of bio-oils over equilibrium FCC catalysts. Contributions from alcohols, phenols and aromatics ethers; Elsevier; Catalysis Today; 212; 9-2013; 10-15-
dc.identifier0920-5861-
dc.identifierhttp://hdl.handle.net/11336/21222-
dc.identifierCONICET Digital-
dc.identifierCONICET-
dc.identifier.urihttp://rodna.bn.gov.ar:8080/jspui/handle/bnmm/304719-
dc.descriptionThe conversions of oxygenated compounds of bio-oils (alcohols, phenols and aromatic ethers) on a equi-librium FCC catalyst were studied at 500◦C during 60 s in a fixed bed laboratory reactor. Methanol,phenol and 2,6-dimethoxyphenol were dissolved in water and 1,2,4-trimethoxybenzene in benzene at5 %wt. Identical experiments were performed over inert SiC. Conversions were very different, the highestone being that of 1,2,4-trimethoxybenzene (95.7 %wt.), followed by 2,6-dimethoxyphenol (75.0 %wt.),methanol (60.8 %wt.) and phenol (54.9 %wt.). Deoxygenation in all the reactants was from dehydrationand decarboxylation. The highest yield of hydrocarbons (47.1 %wt.) and coke (16.0 %wt.) were from 1,2,4-trimethoxybenzene, which, together with methanol, yielded mainly aromatics in the gasoline range. Onthe contrary, phenol and syringol yielded C4-hydrocarbons with high content of olefins. The highestamounts of oxygenated compounds were produced by 2,6-dimethoxyphenol. The thermal conversionswere similar to the catalytic ones in the only case of 1,2,4-trimethoxybenzene, but much lower with theother reactants. In comparison to the catalytic experiments, thermal tests yielded much more hydrocar-bons with 1,2,4-trimethoxybenzene, and oxygenated compounds with 2,6-dimethoxyphenol, than theother reactants. These tests could help in the prediction of specific contributions by these reactants ifbio-oils are co-processed in FCC units or upgraded over acidic catalysts.-
dc.descriptionFil: Bertero, Melisa Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones En Catalisis y Petroquímica "ing. Jose Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones En Catalisis y Petroquímica "ing. Jose Miguel Parera"; Argentina-
dc.descriptionFil: Sedran, Ulises Anselmo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones En Catalisis y Petroquímica "ing. Jose Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones En Catalisis y Petroquímica "ing. Jose Miguel Parera"; Argentina-
dc.formatapplication/pdf-
dc.formatapplication/pdf-
dc.formatapplication/pdf-
dc.languageeng-
dc.publisherElsevier-
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/https://doi.org/10.1016/j.cattod.2013.03.016-
dc.relationinfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0920586113001120-
dc.rightsinfo:eu-repo/semantics/restrictedAccess-
dc.rightshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/-
dc.sourcereponame:CONICET Digital (CONICET)-
dc.sourceinstname:Consejo Nacional de Investigaciones Científicas y Técnicas-
dc.sourceinstacron:CONICET-
dc.source.urihttp://hdl.handle.net/11336/21222-
dc.subjectBio-oils-
dc.subjectCo-processing-
dc.subjectFCC-
dc.subjectFuels-
dc.subjectIngeniería de Procesos Químicos-
dc.subjectIngeniería Química-
dc.subjectINGENIERÍAS Y TECNOLOGÍAS-
dc.titleUpgrading of bio-oils over equilibrium FCC catalysts. Contributions from alcohols, phenols and aromatics ethers-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/publishedVersion-
dc.typeinfo:ar-repo/semantics/articulo-
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