Registro completo de metadatos
| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.creator | Juncal, Luciana Celeste | - |
| dc.creator | Bava, Yanina Belén | - |
| dc.creator | Tamone, Luciana Mariel | - |
| dc.creator | Seng, Samantha | - |
| dc.creator | Tobón, Yeny A. | - |
| dc.creator | Sobanska, Sophie | - |
| dc.creator | Picone, Andrea Lorena | - |
| dc.creator | Romano, Rosana Mariel | - |
| dc.date | 2018-06-14T14:49:23Z | - |
| dc.date | 2018-06-14T14:49:23Z | - |
| dc.date | 2017-06 | - |
| dc.date | 2018-06-12T14:36:50Z | - |
| dc.date.accessioned | 2019-04-29T15:53:23Z | - |
| dc.date.available | 2019-04-29T15:53:23Z | - |
| dc.date.issued | 2017-06 | - |
| dc.identifier | Juncal, Luciana Celeste; Bava, Yanina Belén; Tamone, Luciana Mariel; Seng, Samantha; Tobón, Yeny A.; et al.; Experimental and theoretical investigation on conformational and spectroscopic properties of dimethyl dithiodiglycolate, [CH3OC(O)CH2S]2; Elsevier Science; Journal of Molecular Structure; 1137; 6-2017; 524-529 | - |
| dc.identifier | 0022-2860 | - |
| dc.identifier | http://hdl.handle.net/11336/48630 | - |
| dc.identifier | CONICET Digital | - |
| dc.identifier | CONICET | - |
| dc.identifier.uri | http://rodna.bn.gov.ar:8080/jspui/handle/bnmm/304729 | - |
| dc.description | Dimethyl dithiodiglycolate (DTG), [CH3OC(O)CH2S]2, was synthetized by complete oxidation of methyl thioglycolate (MTG) with I2, and characterized by gas chromatography coupled with electron-impact mass spectrometry. Fifteen stable conformers were found with the B3LYP/6-31 + G* approximation, with calculated populations at ambient temperature higher than 1%. The IR and Raman spectra of liquid DTG were interpreted for the first time, in terms of equilibrium between four conformers. The UV–visible spectra of DTG in solutions of ethanol, isopropanol and acetonitrile present a low-intensity band around 230 nm, interpreted mainly as arising from n → π* transitions localized at the C[dbnd]O groups, according to the prediction of TD-DFT calculations. | - |
| dc.description | Fil: Juncal, Luciana Celeste. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; Argentina | - |
| dc.description | Fil: Bava, Yanina Belén. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; Argentina | - |
| dc.description | Fil: Tamone, Luciana Mariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; Argentina | - |
| dc.description | Fil: Seng, Samantha. Université de Lille 1 Sciences et Technologies; Francia | - |
| dc.description | Fil: Tobón, Yeny A.. Université de Lille 1 Sciences et Technologies; Francia | - |
| dc.description | Fil: Sobanska, Sophie. Université de Lille 1 Sciences et Technologies; Francia | - |
| dc.description | Fil: Picone, Andrea Lorena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; Argentina | - |
| dc.description | Fil: Romano, Rosana Mariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; Argentina | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.language | eng | - |
| dc.publisher | Elsevier Science | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/https://dx.doi.org/10.1016/j.molstruc.2017.02.058 | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0022286017302041 | - |
| dc.rights | info:eu-repo/semantics/openAccess | - |
| dc.rights | https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ | - |
| dc.source | reponame:CONICET Digital (CONICET) | - |
| dc.source | instname:Consejo Nacional de Investigaciones Científicas y Técnicas | - |
| dc.source | instacron:CONICET | - |
| dc.subject | CONFORMATIONAL ANALYSIS | - |
| dc.subject | DFT CALCULATIONS | - |
| dc.subject | VIBRATIONAL SPECTROSCOPY | - |
| dc.subject | Otras Ciencias Químicas | - |
| dc.subject | Ciencias Químicas | - |
| dc.subject | CIENCIAS NATURALES Y EXACTAS | - |
| dc.title | Experimental and theoretical investigation on conformational and spectroscopic properties of dimethyl dithiodiglycolate, [CH3OC(O)CH2S]2 | - |
| dc.type | info:eu-repo/semantics/article | - |
| dc.type | info:eu-repo/semantics/publishedVersion | - |
| dc.type | info:ar-repo/semantics/articulo | - |
| Aparece en las colecciones: | CONICET | |
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