Registro completo de metadatos
| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.creator | Dennehy, Mariana | - |
| dc.creator | Quinzani, Oscar Valentín | - |
| dc.creator | Ferullo, Ricardo | - |
| dc.creator | Granados, Alejandro Manuel | - |
| dc.creator | Burrow, Robert A. | - |
| dc.date | 2018-10-03T19:07:36Z | - |
| dc.date | 2018-10-03T19:07:36Z | - |
| dc.date | 2011-11 | - |
| dc.date | 2018-10-01T15:23:21Z | - |
| dc.date.accessioned | 2019-04-29T15:53:42Z | - |
| dc.date.available | 2019-04-29T15:53:42Z | - |
| dc.date.issued | 2011-11 | - |
| dc.identifier | Dennehy, Mariana; Quinzani, Oscar Valentín; Ferullo, Ricardo; Granados, Alejandro Manuel; Burrow, Robert A.; Aurophilic interaction in gold(I) thiosaccharinates: Synthesis, characterization, crystal structures and DFT theoretical study; Elsevier Science Sa; Inorganica Chimica Acta; 377; 1; 11-2011; 77-83 | - |
| dc.identifier | 0020-1693 | - |
| dc.identifier | http://hdl.handle.net/11336/61575 | - |
| dc.identifier | CONICET Digital | - |
| dc.identifier | CONICET | - |
| dc.identifier.uri | http://rodna.bn.gov.ar:8080/jspui/handle/bnmm/304868 | - |
| dc.description | The reaction of gold with thiosaccharin ligand and additional phosphorous coligands is studied. Four new Au(I) complexes with thiosaccharinate as coordinating counteranion: [Au(tsac)(PPh3)], [Au2(tsac) 2(dppm)]·EtOH, Au2(tsac)2(dppe) ·EtOH, and Au(tsac)(Htsac)2·0.25 EtOH (tsac: thiosaccharinate, C6H4C(S)NSO2 -, dppm: bis(diphenylphosphino)methane, dppe: bis(diphenylphosphino)ethane) were synthesized and characterized by means of spectroscopic techniques (IR, UV-Vis, and 1H, 13C and 13P NMR). The crystal structure of two of them, [Au(tsac)(PPh3)] and [Au2(tsac) 2(dppm)]·EtOH, were solved applying single crystal X-ray diffraction and studied using the density functional theory (DFT) formalism. In the latter, the aurophilic interaction between the two gold centers was analyzed and theoretically confirmed. © 2011 Elsevier B.V. All rights reserved. | - |
| dc.description | Fil: Dennehy, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina | - |
| dc.description | Fil: Quinzani, Oscar Valentín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina | - |
| dc.description | Fil: Ferullo, Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur. Departamento de Física; Argentina | - |
| dc.description | Fil: Granados, Alejandro Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina | - |
| dc.description | Fil: Burrow, Robert A.. Universidade Federal de Santa María; Brasil | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.language | eng | - |
| dc.publisher | Elsevier Science Sa | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/https://dx.doi.org/10.1016/j.ica.2011.07.052 | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0020169311006256 | - |
| dc.rights | info:eu-repo/semantics/restrictedAccess | - |
| dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | - |
| dc.source | reponame:CONICET Digital (CONICET) | - |
| dc.source | instname:Consejo Nacional de Investigaciones Científicas y Técnicas | - |
| dc.source | instacron:CONICET | - |
| dc.subject | AUROPHILICITY | - |
| dc.subject | DFT | - |
| dc.subject | GOLD | - |
| dc.subject | PHOSPHINES | - |
| dc.subject | THIOSACCHARINATE | - |
| dc.subject | X-RAY DIFFRACTION | - |
| dc.subject | Otras Ciencias Químicas | - |
| dc.subject | Ciencias Químicas | - |
| dc.subject | CIENCIAS NATURALES Y EXACTAS | - |
| dc.title | Aurophilic interaction in gold(I) thiosaccharinates: Synthesis, characterization, crystal structures and DFT theoretical study | - |
| dc.type | info:eu-repo/semantics/article | - |
| dc.type | info:eu-repo/semantics/publishedVersion | - |
| dc.type | info:ar-repo/semantics/articulo | - |
| Aparece en las colecciones: | CONICET | |
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