Registro completo de metadatos
| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.creator | Diez, Veronica Karina | - |
| dc.creator | Marcos, B.J. | - |
| dc.creator | Apesteguia, Carlos Rodolfo | - |
| dc.creator | Di Cosimo, Juana Isabel | - |
| dc.date | 2018-08-28T15:28:04Z | - |
| dc.date | 2018-08-28T15:28:04Z | - |
| dc.date | 2009-04 | - |
| dc.date | 2018-08-14T14:32:49Z | - |
| dc.date.accessioned | 2019-04-29T15:56:18Z | - |
| dc.date.available | 2019-04-29T15:56:18Z | - |
| dc.identifier | Diez, Veronica Karina; Marcos, B.J.; Apesteguia, Carlos Rodolfo; Di Cosimo, Juana Isabel; Ionone synthesis by cyclization of pseudoionone on silica-supported heteropolyacid catalysts; Elsevier Science; Applied Catalysis A: General; 358; 1; 4-2009; 95-102 | - |
| dc.identifier | 0926-860X | - |
| dc.identifier | http://hdl.handle.net/11336/57330 | - |
| dc.identifier | CONICET Digital | - |
| dc.identifier | CONICET | - |
| dc.identifier.uri | http://rodna.bn.gov.ar:8080/jspui/handle/bnmm/305751 | - |
| dc.description | The liquid-phase cyclization of pseudoionone to ionones (α, β and γ isomers) was studied on silica-supported heteropolyacid (HPA) catalysts containing between 18.8 and 58.5% HPA. The HPA used was tungstophosphoric acid (H3PW12O40). The catalyst surface and structural properties were thoroughly characterized by several techniques. The density, chemical nature and strength distribution of the surface acid sites were determined by adsorbing and monitoring by temperature-programmed desorption and infrared spectroscopy probe molecules such as NH3 and pyridine. The pseudoionone conversion to ionones increased linearly with the Brønsted acid site density until the HPA loading approached to the monolayer saturation coverage. For higher HPA contents, the pseudoionone adsorption and conversion were hampered because of spatial constraints that diminished the reactant accessibility to the proton active sites. The highest ionone yield, 79%, was obtained on a 58.5 wt% HPA/SiO2 catalyst at 383 K and is comparable to the best values reported in literature for the homogeneously catalyzed reaction using sulfuric acid. The ionone isomer distribution was modified by varying both the temperature and the reaction time. A reaction mechanism was postulated in which ionone isomers (α, β and γ) are primary products, but γ-ionone is isomerized to α-ionone while β-ionone is not converted in the other isomers. | - |
| dc.description | Fil: Diez, Veronica Karina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina | - |
| dc.description | Fil: Marcos, B.J.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina | - |
| dc.description | Fil: Apesteguia, Carlos Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina | - |
| dc.description | Fil: Di Cosimo, Juana Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.language | eng | - |
| dc.publisher | Elsevier Science | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.apcata.2009.02.002 | - |
| dc.rights | info:eu-repo/semantics/restrictedAccess | - |
| dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | - |
| dc.source | reponame:CONICET Digital (CONICET) | - |
| dc.source | instname:Consejo Nacional de Investigaciones Científicas y Técnicas | - |
| dc.source | instacron:CONICET | - |
| dc.subject | Ionone | - |
| dc.subject | Heteropolyacid | - |
| dc.subject | Acid catalysis | - |
| dc.subject | Tungstophosphoric acid | - |
| dc.subject | HPA | - |
| dc.subject | Otras Ingeniería Química | - |
| dc.subject | Ingeniería Química | - |
| dc.subject | INGENIERÍAS Y TECNOLOGÍAS | - |
| dc.title | Ionone synthesis by cyclization of pseudoionone on silica-supported heteropolyacid catalysts | - |
| dc.type | info:eu-repo/semantics/article | - |
| dc.type | info:eu-repo/semantics/publishedVersion | - |
| dc.type | info:ar-repo/semantics/articulo | - |
| Aparece en las colecciones: | CONICET | |
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