Registro completo de metadatos
| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.creator | Sigrist, Mirna Edit | - |
| dc.creator | Beldomenico, Horacio Ramon | - |
| dc.creator | Tudino, Mabel Beatriz | - |
| dc.date | 2019-03-13T20:16:35Z | - |
| dc.date | 2019-03-13T20:16:35Z | - |
| dc.date | 2010-08 | - |
| dc.date | 2019-03-08T20:28:37Z | - |
| dc.date.accessioned | 2019-04-29T15:56:44Z | - |
| dc.date.available | 2019-04-29T15:56:44Z | - |
| dc.identifier | Sigrist, Mirna Edit; Beldomenico, Horacio Ramon; Tudino, Mabel Beatriz; Determination of As(III) in nonacidified groundwater samples for inorganic speciation analysis using flow injection hydride generation atomic absorption spectrometry; Taylor ; Spectroscopy Letters; 43; 6; 8-2010; 458-464 | - |
| dc.identifier | 0038-7010 | - |
| dc.identifier | http://hdl.handle.net/11336/71536 | - |
| dc.identifier | CONICET Digital | - |
| dc.identifier | CONICET | - |
| dc.identifier.uri | http://rodna.bn.gov.ar:8080/jspui/handle/bnmm/305922 | - |
| dc.description | A flow injection system coupled to hydride generation atomic absorption spectrometry with heated quartz tube atomizer was employed for the selective determination of As(III) in real groundwater samples under nonacidic conditions. The use of low-acidity conditions was carefully evaluated in order to minimize the interconversion of redox arsenic species. The As(III) hydride was generated using 0.1 mol L-1 HCl as carrier solution and 0.2% (m/v) NaBH4 in 0.025% NaOH as the reductant. A coil reaction larger than the used one for higher acidity conditions (480 mm instead of 115 mm) was selected. The generated hydride was transported to the atomizer by a nitrogen flow of 75 ml min-1. The main parameters that influenced the signal intensity and shape were studied. Under the best found experimental conditions, a detection limit (3σ) of 1.0 μgL-1 As(III) was obtained for a 500 μl sample volume. The analytical recovery ranged between 90% and 98%. In addition, the total inorganic arsenic concentration in the samples was determined on sample aliquots acidified with concentrated HCl and prereduced with 5% (m/v) KI-5% (m/v) C6H8O6 solution. HCl 1.2 mol L-1 as carrier solution, NaBH4 0.2% (m/v) as reductant, and a nitrogen flow rate of 75 ml min-1 were used in this case. The concentration of As(V) was calculated by difference between the total inorganic arsenic and As(III) concentrations. © Taylor & Francis Group, LLC. | - |
| dc.description | Fil: Sigrist, Mirna Edit. Universidad Nacional del Litoral. Facultad de Ingeniería Química; Argentina | - |
| dc.description | Fil: Beldomenico, Horacio Ramon. Universidad Nacional del Litoral. Facultad de Ingeniería Química; Argentina | - |
| dc.description | Fil: Tudino, Mabel Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.language | eng | - |
| dc.publisher | Taylor | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/https://dx.doi.org/10.1080/00387010903261214 | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/abs/10.1080/00387010903261214 | - |
| dc.rights | info:eu-repo/semantics/restrictedAccess | - |
| dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | - |
| dc.source | reponame:CONICET Digital (CONICET) | - |
| dc.source | instname:Consejo Nacional de Investigaciones Científicas y Técnicas | - |
| dc.source | instacron:CONICET | - |
| dc.subject | ARSENIC SPECIATION | - |
| dc.subject | ATOMIC ABSORPTION SPECTROMETRY | - |
| dc.subject | FLOW INJECTION | - |
| dc.subject | HYDRIDE GENERATION | - |
| dc.subject | NONACIDIFIED WATER SAMPLES | - |
| dc.subject | Otras Ciencias Químicas | - |
| dc.subject | Ciencias Químicas | - |
| dc.subject | CIENCIAS NATURALES Y EXACTAS | - |
| dc.title | Determination of As(III) in nonacidified groundwater samples for inorganic speciation analysis using flow injection hydride generation atomic absorption spectrometry | - |
| dc.type | info:eu-repo/semantics/article | - |
| dc.type | info:eu-repo/semantics/publishedVersion | - |
| dc.type | info:ar-repo/semantics/articulo | - |
| Aparece en las colecciones: | CONICET | |
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