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dc.creatorGañan, Nicolas Alberto-
dc.creatorDambolena, Jose Sebastian-
dc.creatorMartini, Raquel Evangelina-
dc.creatorBottini, Susana Beatriz-
dc.date2016-12-28T18:18:52Z-
dc.date2016-12-28T18:18:52Z-
dc.date2015-03-
dc.date2016-12-27T20:27:59Z-
dc.date.accessioned2019-04-29T15:56:47Z-
dc.date.available2019-04-29T15:56:47Z-
dc.identifierGañan, Nicolas Alberto; Dambolena, Jose Sebastian; Martini, Raquel Evangelina; Bottini, Susana Beatriz; Supercritical carbon dioxide fractionation of peppermint oil with low menthol content: experimental study and simulation analysis for the recovery of piperitenone; Elsevier Science; Journal of Supercritical Fluids; 98; 3-2015; 1-11-
dc.identifier0896-8446-
dc.identifierhttp://hdl.handle.net/11336/10518-
dc.identifier.urihttp://rodna.bn.gov.ar:8080/jspui/handle/bnmm/305940-
dc.descriptionLow-menthol or dementholized oils can be regarded as potential sources of biocidal compounds, particularly monoterpenic ketones such as menthone, piperitone, piperitenone, pulegone and carvone. In this work, the recovery of piperitenone from peppermint oil by supercritical carbon dioxide fractionation is studied. Separation selectivity and gas loading measurements were performed in a semicontinuous high-pressure apparatus in order to evaluate the effect of temperature and solvent density on these properties. Semicontinuous fractionation was also carried out at a fixed temperature (313 K) and pressure (85 bar), collecting and analyzing extract samples until a purified piperitenone raffinate was obtained. The phase behavior of the system was modeled and predicted with the group contribution equation of state (GC-EOS). Good agreement with the experimental results was obtained. Finally, a continuous countercurrent multistage fractionation process was simulated, based on the GC-EOS model. The effect of operation temperature and pressure, solvent-to-feed ratio and reflux ratio was studied for different purity and recovery requirements and oil feed compositions.-
dc.descriptionFil: Gañan, Nicolas Alberto. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Bahia Blanca. Planta Piloto de Ingenieria Quimica (i). Grupo Vinculado Al Plapiqui - Inv. y Desarrollo En Tecnologia Quimica; Argentina. Universidad Nacional de Córdoba; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Ciencia y Tecnología de Alimentos Córdoba; Argentina-
dc.descriptionFil: Dambolena, Jose Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto Multidisciplinario de Biología Vegetal (p); Argentina. Universidad Nacional de Córdoba; Argentina-
dc.descriptionFil: Martini, Raquel Evangelina. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro Cientifico Tecnol.conicet - Bahia Blanca. Planta Piloto de Ingenieria Quimica (i). Grupo Vinculado Al Plapiqui - Inv. y Desarrollo En Tecnologia Quimica; Argentina-
dc.descriptionFil: Bottini, Susana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur; Argentina-
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dc.languageeng-
dc.publisherElsevier Science-
dc.relationinfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S089684461400429X-
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.supflu.2014.12.018-
dc.rightsinfo:eu-repo/semantics/restrictedAccess-
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/-
dc.sourcereponame:CONICET Digital (CONICET)-
dc.sourceinstname:Consejo Nacional de Investigaciones Científicas y Técnicas-
dc.sourceinstacron:CONICET-
dc.subjectPEPPERMINT OIL-
dc.subjectSUPERCRITICAL FLUID FRACTIONATION-
dc.subjectGC-EOS-
dc.subjectCOUNTERCURRENT FRACTIONATION-
dc.subjectOtras Ingeniería Química-
dc.subjectIngeniería Química-
dc.subjectINGENIERÍAS Y TECNOLOGÍAS-
dc.titleSupercritical carbon dioxide fractionation of peppermint oil with low menthol content: experimental study and simulation analysis for the recovery of piperitenone-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/publishedVersion-
dc.typeinfo:ar-repo/semantics/articulo-
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